Answer:
a. Minimum 1.70 V
b. There is no maximum.
Explanation:
We can solve this question by remembering that the cell potential is given by the formula
ε⁰ cell = ε⁰ reduction - ε⁰ oxidation
Now the problem states the cell must provide at least 0.9 V and that the reduction potential of the oxidized species 0.80 V, thus
ε⁰ reduction - ε⁰ oxidation ≥ ε⁰ cell
Since ε⁰ oxidation is by definition the negative of ε⁰ reduction , we have
ε⁰ reduction - ( 0.80 V ) ≥ 0.90 V
⇒ ε⁰ reduction ≥ 1.70 V
Therefore,
(a) The minimum standard reduction potential is 1.70 V
(b) There is no maximum standard reduction potential since it is stated in the question that we want to have a cell that provides at leat 0.9 V
that seems very false but I believe its the second one
Answer:
Niels Bohr, refined the model of an atom by proposing a quantized shell structure atomic model in order to describe how the electrons are able to maintain stable orbits around the nucleus
Based on the predictions of classical mechanics the electron motion of the Rutherford model was unstable as the electrons where expected to have lost some energy during motion and thus having to come rest in the nucleus
According to the modification by Neils Bohr in 1913, electrons move in shells or orbits of fixed energy and emission of electromagnetic radiation takes place only when electrons changes the orbit in which they move
Explanation:
PH of a solution will be <span>higher than 7
</span>
Ammonium cyanide is a salt formed by hydrogen cyanide and ammonia. Ammonia is a weak base and hydrogen cyanide is a weak acid.
NH₄CN + H₂O ⇒ NH₃ + HCN
NH₄⁺ + H₂O -----> H₃O⁺ + NH₃
CN⁻ + H₂O -----> HCN + OH⁻
Although both compounds are weak electrolytes, NH₃ is somewhat stronger base than HCN is a strong acid, so the solution reacts alkaline. We can prove this using Ka and Kb values:
Ka(HCN) = 4.9 x × 10⁻¹⁰
Kb(NH₃) = 1.8 × 10⁻⁵<span>
Kw= </span>1.0 × 10⁻¹⁴
Let's first calculate Ka for NH₄⁺:
Ka(NH₄⁺) x Kb(NH₃<span>) = pKw
</span>Ka(NH₄⁺) = Kw/Kb(NH₃) = 5.6 x 10⁻¹⁰
Then, Kb for CN⁻:
Kb(CN⁻) x Ka(HCN) = pKw
Kb(CN⁻) = Kw/Ka(HCN) = 2 x 10⁻⁵
From this, we can see that the acid constant NH4⁺ is much lower than the base constant of CN⁻, which will say that the solution of NH₄CN will react slightly alkaline because of the higher presence of hydroxyl ions in solution.
Answer:
87.27 grams
Explanation:
The mole ratio of nitrogen to hydrogen is 1:3; while that one of hydrogen to the products (ammonia) is 3:2
Thus if 3 moles of hydrogen gas produce 2 moles of ammonia gas
7.7 moles of hydrogen will produce:
(7.7moles×2)/3
77/15 moles
1 mole of ammonia gas has a mass of 14+3=17
since the mass of an atom of nitrogen is 14 while that of hydrogen atom is 1.
Therefore 77/15 moles will have a mass of
77/15 moles × 17=87.27 grams
