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Answer:
The required volume of hexane is 0.66245 Liters.
Explanation:
Volume of octane = v=1.0 L=
Density of octane= d = 
Mass of octane ,m= 
Moles of octane =
Mole percentage of Hexane = 45%
Mole percentage of octane = 100% - 45% = 55%

Total moles = 11.212 mol
Moles of hexane :

Moles of hexane = 5.0454 mol
Mass of 5.0454 moles of hexane,M = 5.0454 mol × 86 g/mol=433.9044 g
Density of the hexane,D = 
Volume of hexane = V

(1 cm^3= 0.001 L)
The required volume of hexane is 0.66245 Liters.