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oksano4ka [1.4K]
3 years ago
15

The pressure on a sample of gas is increased from 1.0 atm to 3.0 atm. If the new volume is 0.52 L, find the original volume.

Chemistry
1 answer:
swat323 years ago
3 0

Answer: 1.56 ATM

Explanation: if we assume temperature is constant, gas obeys

Boyles law pV= constant. Then p1·V1= p2·V2. And V1 = p2V2/p1

= 3.0 atm·0,52 l / 1.0 atm

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Consider the data presented below. time (s) 0 40 80 120 160 moles of a 0.100 0.067 0.045 0.030 0.020 part a part complete determ
Whitepunk [10]
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows 
time         0         40        80       120       160
moles    0.100   0.067  0.045    0.030    0.020


Q1)
for the first 40 s change of moles ;
      = -d[A] / t
      = - (0.067-0.100)/40s
      = 8.25 x 10⁻⁴ mol/s
for the next 40 s
      = -(0.045-0.067)/40
      = 5.5 x 10⁻⁴ mol/s
the 40 s after that
      = -(0.030-0.045)/40 s 
     = 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction

rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ   -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction

Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation. 
Since this is a first order reaction,
b = 1
therefore the reaction is 
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
   = 8.25 x 10⁻³ s⁻¹

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