<u>Answer:</u> The correct statement is low temperature only, because entropy decreases during freezing.
<u>Explanation:</u>
The relationship between Gibb's free energy, enthalpy, entropy and temperature is given by the equation:
Where,
= change in Gibb's free energy
= change in enthalpy
T = temperature
= change in entropy
It is given that freezing of methane is taking place, which means that entropy is decreasing and 
is becoming negative. It is also given that the reaction is an exothermic reaction, this means that the is also negative.
For a reaction to be spontaneous, must be negative.
![-ve=-ve-[T(-ve)]\\\\-ve=-ve+T](https://tex.z-dn.net/?f=-ve%3D-ve-%5BT%28-ve%29%5D%5C%5C%5C%5C-ve%3D-ve%2BT)
From above equations, it is visible that will be negative only when the temperature will be low.
Hence, the correct statement is low temperature only, because entropy decreases during freezing.
Answer:
Option-4 (3:2) is the correct answer.
Explanation:
Following steps are taken to balance the given unbalanced chemical equation.
Step 1: Write the unbalanced chemical equation,
N₂ + H₂ → NH₃
Step 2: Balance Nitrogen Atoms;
There are 2 nitrogen atoms on left hand side and 1 nitrogen atoms on right hand site therefore, to balance them multiply NH₃ on right hand side by 2 i.e.
N₂ + H₂ → 2 NH₃
Step 3: Balance Hydrogen Atoms;
Now, there are 2 hydrogen atoms on left hand side and 6 hydrogen atom on right hand site therefore, to balance them multiply H₂ on left hand side by 3 i.e.
N₂ + 3 H₂ → 2 NH₃
Now, the equation is balanced.
Step 4: Finding out mole ratios:
From balanced chemical equation it can be concluded that 3 moles of H₂ are involved in producing 2 moles of NH₃ hence, the mole ratio of consumption of H₂ to production of NH₃ is 3:2.
The combination sounds like it'd be a powerful disinfectant, but the two should never be mixed. "Together, they produce chlorine gas, which even at low levels, can cause coughing, breathing problems, and burning, watery eyes," says Forte.
