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Snezhnost [94]
3 years ago
12

A sample of g of pure aluminum metal is added to mL of M hydrochloric acid. The volume of hydrogen gas produced at standard temp

erature and pressure is
Chemistry
1 answer:
MArishka [77]3 years ago
3 0

Answer:

V = 11.2L are produced

Explanation:

... <em>Sample of 27g of pure aluminium, 3added to 333 mL of 3.0 M HCl..</em>

Based on the chemical reaction:

2Al(s) + 6HCl(aq) → 2AlC₃(aq) + 3H₂(g)

<em>Where 3 moles of hydrogen are produced when 6 moles of hydrochloric acid reacts with 2 moles of Al.</em>

<em />

To solve this question, we need to determine limiting reactant converting each reactant to moles. With limiting reactant and the chemical reaction we can find moles of hydrogen and its volume at STP (T=273.15K; P=1atm), thus:

<em>Moles Al-Molar mass: 26.98g/mol-:</em>

27g * (1mol / 26.98g) = 1mol of Al

<em>Moles HCl:</em>

333mL = 0.333L * (3mol/L) = 1mol HCl

For a complete reaction of 1 mole of HCl are required:

1mol HCl * (2mol Al / 6mol HCl) = 0.333 moles of Al. As there is 1 mole of Al, Al is in excess and <em>HCl is limiting reactant.</em>

<em />

Moles of Hydrogen produced are:

1mol HCl * (3 moles H₂ / 6 mol HCl) = 0.5moles H₂ are produced.

Using ideal gas law:

PV = nRT

V = nRT/P

<em>Where V is volume</em>

<em>n are moles: 0.5mol</em>

<em>R is gas constant: 0.082atmL/molK</em>

<em>T is absolute temperature: 273.15K</em>

<em>P is pressure: 1atm.</em>

<em />

Solving for V:

V = 0.5mol*0.082atmL/molK*273.15K / 1atm

<h3>V = 11.2L are produced</h3>
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3 years ago
Determine the [OH−] of a solution that is 0.115 M in CO32−. For carbonic acid (H2CO3), Ka1=4.3×10−7 and Ka2=5.6×10−11.
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Answer:

[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.

Explanation:

Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.

Analysis:

            H₂CO₃(aq)     ⇄     H⁺(aq)    +    HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷

C(i)          0.115M                      0                  0

ΔC              -x                        +x                  +x

C(eq)    0.115M - x                   x                    x

            ≅ 0.115M

Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M

= 4.3 x 10⁻⁷  => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.

In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion  concentration, the hydroxide ion concentration is then calculated from

[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.

________________________________________________________

NOTE: The 2.32 x 10⁻⁴M  value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.

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