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antiseptic1488 [7]
3 years ago
13

Tin has ten stable isotopes. The heaviest, 124Sn, makes up 5.80% of naturally occuring tin atoms. How many atoms of 124Sn are pr

esent in 82.0 g of naturally occurring tin? What is the total mass of the 124Sn atoms in this sample?
Chemistry
1 answer:
matrenka [14]3 years ago
5 0

The average atomic mass of Sn is 118.71 g/mol

the percentage of heaviest Sn is 5.80%

the given mass of Sn is 82g

The total  moles of Sn will be = mass / atomic mass = 82/118.71=0.691

Total atoms of Sn in 82g = 6.023X10^{23}X0.691=4.16X10^{23}

the percentage of heaviest Sn is 5.80%

So the total atoms of Sn^{124} = 5.80% X 4.16X10^{23}

Total atoms of Sn^{124}=2.41X10^{22} atoms

the mass of Sn^{124} will be = \frac{2.41X10^{22}X124}{6.023X10^{23}}=4.96g

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Calculate the solubilities of the following compounds in a 0.02 M solution of barium nitrate using molar concentrations, first i
Law Incorporation [45]

Answer:

a. 1.7 × 10⁻⁴ mol·L⁻¹; b. 5.5 × 10⁻⁹ mol·L⁻¹

c. 2.3 × 10⁻⁴ mol·L⁻¹;    5.5 × 10⁻⁸ mol·L⁻¹

Explanation:

a. Silver iodate

Let s = the molar solubility.  

                     AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq); Ksp = 3.0 × 10⁻⁸

E/mol·L⁻¹:                               s               s

K_{sp} =\text{[Ag$^{+}$][IO$_{3}$$^{-}$]} = s\times s =  s^{2} = 3.0\times 10^{-8}\\s = \sqrt{3.0\times 10^{-8}} \text{ mol/L} = 1.7 \times 10^{-4} \text{ mol/L}

b. Barium sulfate

                     BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq); Ksp = 1.1 × 10⁻¹⁰

I/mol·L⁻¹:                                0.02             0

C/mol·L⁻¹:                                 +s              +s

E/mol·L⁻¹:                            0.02 + s          s

K_{sp} =\text{[Ba$^{2+}$][SO$_{4}$$^{2-}$]} = (0.02 + s) \times s \approx  0.02s = 1.1\times 10^{-10}\\s = \dfrac{1.1\times 10^{-10}}{0.02} \text{ mol/L} = 5.5 \times 10^{-9} \text{ mol/L}

c. Using ionic strength and activities

(i) Calculate the ionic strength of 0.02 mol·L⁻¹ Ba(NO₃)₂

The formula for ionic strength is  

\mu = \dfrac{1}{2} \sum_{i} {c_{i}z_{i}^{2}}\\\\\mu = \dfrac{1}{2} (\text{[Ba$^{2+}$]}\cdot (2+)^{2} + \text{[NO$_{3}$$^{-}$]}\times(-1)^{2}) = \dfrac{1}{2} (\text{0.02}\times 4 + \text{0.04}\times1)= \dfrac{1}{2} (0.08 + 0.04)\\\\= \dfrac{1}{2} \times0.12 = 0.06

(ii) Silver iodate

a. Calculate the activity coefficients of the ions

\log \gamma = -0.51z^{2}\sqrt{I} = -0.051(1)^{2}\sqrt{0.06} = -0.51\times 0.24 = -0.12\\\gamma = 10^{-0.12} = 0.75

b. Calculate the solubility

AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq)

K_{sp} =\text{[Ag$^{+}$]$\gamma_{Ag^{+}}$[IO$_{3}$$^{-}$]$\gamma_{IO_{3}^{-}}$} = s\times0.75\times s \times 0.75 =0.56s^{2}= 3.0 \times 10^{-8}\\s^{2} = \dfrac{3.0 \times 10^{-8}}{0.56} = 5.3 \times 10^{-8}\\\\s =2.3 \times 10^{-4}\text{ mol/L}

(iii) Barium sulfate

a. Calculate the activity coefficients of the ions

\log \gamma = -0.51z^{2}\sqrt{I} = -0.051(2)^{2}\sqrt{0.06} = -0.51\times16\times 0.24 = -0.50\\\gamma = 10^{-0.50} = 0.32

b. Calculate the solubility

BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq

K_{sp} =\text{[Ba$^{2+}$]$\gamma_{ Ba^{2+}}$[SO$_{4}$$^{2-}$]$\gamma_{ SO_{4}^{2-}}$} = (0.02 + s) \times 0.32\times s\times 0.32 \approx  0.02\times0.10s\\2.0\times 10^{-3}s = 1.1 \times 10^{-10}\\s = \dfrac{1.1\times 10^{-10}}{2.0 \times 10^{-3}} \text{ mol/L} = 5.5 \times 10^{-8} \text{ mol/L}

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2 years ago
Why is there a bond between the ions in potassium chloride
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Answer:

Explanation:

When the two atoms are in contact, potassium transfers its outer electron to chlorine which readily accepts it, resulting in both atoms achieving a state of eight outermost electrons. With this electron transfer, the ionic bond in KCl is formed.

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3 years ago
How do I do 1-2? Do I use graph paper?
sergejj [24]
This would equal -1 or negative one
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3 years ago
Which is a property of matter that you CANNOT observe just by looking at an object?
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Answer:b

Explanation:

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2 years ago
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A gas produced as a by-product from the carbonization of coal has the following composition, mole %: carbon dioxide 4, carbon mo
rewona [7]

Answer:

6059.63 kcal/kg.

Explanation:

CH4 consist of Hydrogen and carbon. Therefore, Hydrogen in CH4 = 12 × 4 = 48 kg,  carbon in CH4 = 12 × 12 = 144kg.

For ethane, the amount of hydrogen present = 2 × 6 = 12kg and that of carbon in ethane = 2 × 24 = 48kg.

The weight of carbon in CO = 15 × 12 = 18kg and the weight of Hydrogen in CO = 15 × 16 = 240kg.

For hydrogen, its weight in H2 = 50 × 2 = 100kg.

For CO2, carbon has = 4 × 12 = 48 kg and oxygen has = 4 × 32 = 128kg.

For C6H6, carbon has 2 × 72 = 144kg and hydrogen has 2 × 6 = 12kg.

For N2, the amount of nitrogen= 11 × 28 = 308 kg.

For CH2= CH2, carbon has 4 × 24 = 96kg and hydrogen = 4 × 4 = 16kg.

The gross calofiric value = 1/100 [ 8080 C + 34500 + ( H - O/8) + 22405].

Where the total weight = 128 + 180+ 48 + 240 + 100 + 144 + 48 + 12 + 48 + 16 + 96 + 308 + 12 + 144 = 1524 kg.

The percentage by weight of carbon = total weight of carbon/total weight × 100.

The total Weight of carbon= 48 + 180 + 144 + 48 +144 + 96 = 660kg.

The percentage weight of carbon = 660/1524 × 100 = 43.3 %.

The percentage weight of hydrogen = total weight of hydrogen/total weight × 100.

The total weight of hydrogen = 100 + 12 + 48 + 16 +12 = 188.

The percentage weight of Hydrogen = 188/ 1524 × 100 = 12.33%.

Percentage weight of oxygen = total weight of oxygen/total weight × 100.

Percentage weight of oxygen = ( 128 + 240) / 1524 × 100 = 24.15%.

The gross calorific value = 1/100 [ 8080 × 43.3 ,+ 34500 ( 13.33 - 24.15/8) ] = 6711.02 kcal/kg.

Net calorific value = 6711.02 - 0.09 × 12.3 × 587 = 6059.63kcal/kg.

5 0
2 years ago
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