propose a synthetic route for the synthesis of a named alkanal starting with ethyl formate and grignard reagent.
1 answer:
Answer:
See explanation and image attached
Explanation:
A Grignard reagent is an alkyl magnesium halide. If it reacts with ethyl formate, an intermediate is formed as shown.
This intermediate can undergo water hydrolysis to form a diol, ethanol and MgBrOH.
Oxidation of the diol obtained now yields the corresponding alkanal which in this case is ethanal.
The scheme of the reaction is shown in the image attached to this answer.
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Answer:
Only gives spontaneous reaction.
Explanation:
A redox reaction will be spontaneous if standard reduction potential () of the reaction is positive. Because it leads to negative standard gibbs free energy change (
), which is a thermodynamic condition for spontaneity of a reaction.
Where and
represents standard reduction potential of reduction half cell and standard reduction potential of oxidation half cell.
(1) Oxidation: ;
Reduction: ;
So,
Hence this pair will give spontaneous reaction.
(2) Similarly as above,
Hence this pair will give non-spontaneous reaction.
(3) Similarly as above,
Hence this pair will give non-spontaneous reaction.
(4) Similarly as above,
Hence this pair will give non-spontaneous reaction.