Answer:
k = 4.21 * 10⁻³(L/(mol.s))
Explanation:
We know that
k = Ae ------------------- euqation (1)
K= rate constant;
A = frequency factor = 4.36 10^11 M⁻¹s⁻¹;
E = activation energy = 93.1kJ/mol;
R= ideal gas constant = 8.314 J/mol.K;
T= temperature = 332 K;
Put values in equation 1.
k = 4.36*10¹¹(M⁻¹s⁻¹)e
k = 4.2154 * 10⁻³(M⁻¹s⁻¹)
here M =mol/L
k = 4.21 * 10⁻³((mol/L)⁻¹s⁻¹)
or
k = 4.21 * 10⁻³((L/mol)s⁻¹)
or
k = 4.21 * 10⁻³(L/(mol.s))
Answer:
The tube surface temperature immediately after installation is 120.4°C and after prolonged service is 110.8°C
Explanation:
The properties of water at 100°C and 1 atm are:
pL = 957.9 kg/m³
pV = 0.596 kg/m³
ΔHL = 2257 kJ/kg
CpL = 4.217 kJ/kg K
uL = 279x10⁻⁶Ns/m²
KL = 0.68 W/m K
σ = 58.9x10³N/m
When the water boils on the surface its heat flux is:
For copper-water, the properties are:
Cfg = 0.0128
The heat flux is:
qn = 0.9 * 18703.42 = 16833.078 W/m²
The tube surface temperature immediately after installation is:
Tinst = 100 + 20.4 = 120.4°C
For rough surfaces, Cfg = 0.0068. Using the same equation:
ΔT = 10.8°C
The tube surface temperature after prolonged service is:
Tprolo = 100 + 10.8 = 110.8°C