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Anestetic [448]
2 years ago
13

If air contains 78% Nitrogen by volume, what is the solubility of nitrogen in water at 25 degree celisus​

Chemistry
1 answer:
Svet_ta [14]2 years ago
7 0

The solubility of nitrogen in water at 25 °C= 4.88 x 10⁻⁴ mol/L

<h3>Further explanation</h3>

Given

78% Nitrogen by volume

Required

The solubility of nitrogen in water

Solution

Henry's Law states that the solubility of a gas is proportional to its partial pressure  

Can be formulated  

S = kH. P.  

S = gas solubility, mol / L  

kH = Henry constant, mol / L.atm  

P = partial gas pressure  

In the standard 25 C state, the air pressure is considered to be 1 atm, so the partial pressure of N₂ -nitrogen becomes:

Vn / Vtot = Pn / Ptot

78/100 = Pn / 1

Pn = 0.78 atm

Henry constant for N₂ at 25 °c = 1600 atm/mol.L=6.25.10⁻⁴ mol/L.atm

The solubility :

\tt S=6.25.10^{-4}\times 0.78\\\\S=4.88\times 10^{-4}~mol/L

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Answer : The theoretical yield of HCl is, 56.1735 grams

Explanation : Given,

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First we have to calculate the moles of BCl_3 and H_2O.

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The balanced chemical reaction is,

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As, 1 mole of BCl_3 react with 3 mole of H_2O

So, 0.513 moles of BCl_3 react with 3\times 0.513=1.539 moles of H_2O

From this we conclude that, H_2O is an excess reagent because the given moles are greater than the required moles and BCl_3 is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of HCl.

As, 1 mole of BCl_3 react to give 3 moles of HCl

So, 0.513 moles of BCl_3 react to give 3\times 0.513=1.539 moles of HCl

Now we have to calculate the mass of HCl.

\text{Mass of }HCl=\text{Moles of }HCl\times \text{Molar mass of }HCl

\text{Mass of }HCl=(1.539mole)\times (36.5g/mole)=56.1735g

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