1. Which processes are taking place in the system represented by the following equation?
1 answer:
For the first question:
The double directional arrow (<span>→←) shows that the equation is moving at both directions (forward and reverse) simultaneously (at the same time).
So for the equation, two processes are happening at the same time:
1- Carbon monoxide combines with oxygen to form carbon dioxide
2CO2 + O2 ..........> 2CO2
2- Carbon dioxide dissociates to give carbon monoxide and oxygen
2CO + O2 <........ 2CO2
For the second question:
The equilibrium constant can be calculated as shown in the attached picture.
Applying this rule to the given equation, we find that:
k= [(0.01^1)(0.01^1)] / [(0.8^2)] = 1.5625 x 10^-4</span>
The double directional arrow (<span>→←) shows that the equation is moving at both directions (forward and reverse) simultaneously (at the same time).
So for the equation, two processes are happening at the same time:
1- Carbon monoxide combines with oxygen to form carbon dioxide
2CO2 + O2 ..........> 2CO2
2- Carbon dioxide dissociates to give carbon monoxide and oxygen
2CO + O2 <........ 2CO2
For the second question:
The equilibrium constant can be calculated as shown in the attached picture.
Applying this rule to the given equation, we find that:
k= [(0.01^1)(0.01^1)] / [(0.8^2)] = 1.5625 x 10^-4</span>
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The equation for the first dissociation is:
H₂S(aq) + H₂O(l) ⇄ HS⁻(aq) + H₃O⁺(aq)
The acid dissociation constant, Ka1 is 9.0 x 10⁻⁸
Construct ICE table and obtain their equilibrium concentrations:
H₂S(aq) + H₂O(l) ⇄ HS⁻(aq) + H₃O⁺(aq)
I (M): 0.1 0 0
C (M): -x +x +x
E (M): 0.1 -x x x
So:
9.0 x 10⁻⁸ =
x = 9.4 x 10⁻⁵
From the equilibrium table:
[H₃O⁺] = x = 9.4 X 10⁻⁵ M
[HS⁻] = x = 9.4 X 10⁻⁵ M
The equation for the second dissociation of the acid is:
HS⁻(aq) + H₂O(l) ⇄ S⁻²(aq) + H₃O⁺(aq)
The acid dissociation constant Ka2 is 1.0 x 10⁻¹⁷
Construct ICE table and obtain their equilibrium concentrations:
HS⁻(aq) + H₂O(l) ⇄ S²⁻(aq) + H₃O⁺(aq)
I (M): 9.4 x 10⁻⁵ 0 9.4 x 10⁻⁵
C (M): -x +x +x
E (M): 9.4 x 10⁻⁵ -x x 9.4 x 10⁻⁵ + x
So:
1.0 x 10⁻¹⁷ =
x = 1.0 x 10⁻¹⁷ M
Therefore the equilibrium concentrations are as follows:
[S²⁻] = x = 1.0 x 10⁻¹⁷ M
[H₃O⁺] = 9.4 x 10⁻⁵ + 1.0 x 10⁻¹⁷ M = 9.4 x 10⁻⁵ M
H₂S(aq) + H₂O(l) ⇄ HS⁻(aq) + H₃O⁺(aq)
The acid dissociation constant, Ka1 is 9.0 x 10⁻⁸
Construct ICE table and obtain their equilibrium concentrations:
H₂S(aq) + H₂O(l) ⇄ HS⁻(aq) + H₃O⁺(aq)
I (M): 0.1 0 0
C (M): -x +x +x
E (M): 0.1 -x x x
So:
9.0 x 10⁻⁸ =
x = 9.4 x 10⁻⁵
From the equilibrium table:
[H₃O⁺] = x = 9.4 X 10⁻⁵ M
[HS⁻] = x = 9.4 X 10⁻⁵ M
The equation for the second dissociation of the acid is:
HS⁻(aq) + H₂O(l) ⇄ S⁻²(aq) + H₃O⁺(aq)
The acid dissociation constant Ka2 is 1.0 x 10⁻¹⁷
Construct ICE table and obtain their equilibrium concentrations:
HS⁻(aq) + H₂O(l) ⇄ S²⁻(aq) + H₃O⁺(aq)
I (M): 9.4 x 10⁻⁵ 0 9.4 x 10⁻⁵
C (M): -x +x +x
E (M): 9.4 x 10⁻⁵ -x x 9.4 x 10⁻⁵ + x
So:
1.0 x 10⁻¹⁷ =
x = 1.0 x 10⁻¹⁷ M
Therefore the equilibrium concentrations are as follows:
[S²⁻] = x = 1.0 x 10⁻¹⁷ M
[H₃O⁺] = 9.4 x 10⁻⁵ + 1.0 x 10⁻¹⁷ M = 9.4 x 10⁻⁵ M