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kogti [31]
3 years ago
5

What would you predict for the lengths of the bonds in no2− relative to n−o single bonds and double bonds?

Chemistry
2 answers:
djverab [1.8K]3 years ago
8 0

The bonds in no2− relative to n−o

Ierofanga [76]3 years ago
3 0

Answer:

Single bond > Bond in NO₂  > Double bond

Explanation:

<em>What would you predict for the lengths of the bonds in NO₂ relative to NO single bonds and double bonds?</em>

Let's look at the Lewis structures for NO₂. As we can see, it can be represented by 2 resonant structures. We could picture it as N having a single covalent bond with each O and another single covalent bond that is divided by the two bonds. The resulting bond order is 1.5.

As a general rule, the higher the bond order (B.O.), the shorter the bond length. The rank of lengths is:

Single bond (B.O.: 1) > Bond in NO₂ (B.O.: 1.5) > Double bond (B. O.: 2)

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rank the four gases (air, exhaled air, gas produced from the decomposition of H2O2, gas from decomposition of NaHCO3, in order o
SVEN [57.7K]

Answer: H₂O₂ (94%) > Air (23%) > Exhaled air (13%) > NaHCO₃ (0%)


Initial important note:


Although NaHCO₃ contents oxygen atoms, and you can calculate its compositoin, the resulting gas does not containg pure oxygen gas (O₂). For the comparisson it is not useful to calculate the content of oxygent atoms, but the concentration of O₂ gas. As such, the gas from NaHCO₃ contains 0% of pure O₂, that is why it is ranked last.


1) Air:


Source: internet


Approximate 23%. It is variable, because air is not a pure substance but a mixture of gases, whose compositon is not unique.


2) Exhaled air:


Source: internet.


Approximate 13%. The compositon of the air changes in our lungs, due to the respiration process: we inhale fresh air with around 23% of oxygen, part of this oxygen pass to the cells (lungs - blood - heart - cells) and then it is exhaled with a lower content of air and a greater content of CO₂


3) Air from the decomposition of H₂O₂.


In this case we can do a chemical calculation, since we can state the chemical equation of the reaction:


i) Chemical Equation:


H₂O₂ (g) → H₂ (g) + O₂ (g)


ii) mole ratio of the products 1 mol H₂ : 1 mol O₂


iii) convert moles into mass (grams)


1 mol H₂ × 2 × 1.008 g/mol = 2.016 g


1 mol O₂ × 2 × 15.999 g/mol = 31.998 g


Composition, % = [31.998 g / (2.016 g + 31.998 g) ] × 100 ≈ 94%



4) Air from the decomposition of NaHCO₃:


i) chemical equation:


2 NaHCO₃(s) → Na₂CO₃(s) + CO₂(g) + H₂O(g)


ii) mole ratio: take into account only the gases in the products:


1 mol CO₂ (g) : 1 mol H₂O


iii) mass in grams


CO₂: molar mass ia approximately 44.01 g/mol


H₂O: molar mass is approximately 18.02 g/mol


iii) Those gases although have oxygen atoms, do not hae free oxygen gas, which is what we are compariing. That means, that from the decomposition of NaHCO₃ you get 0% oxygen gas.


5) The result is:


H₂O₂ (94%) > Air (23%) > Exhaled air (13%) > NaHCO₃ (0%)

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3 years ago
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