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kogti [31]
3 years ago
5

What would you predict for the lengths of the bonds in no2− relative to n−o single bonds and double bonds?

Chemistry
2 answers:
djverab [1.8K]3 years ago
8 0

The bonds in no2− relative to n−o

Ierofanga [76]3 years ago
3 0

Answer:

Single bond > Bond in NO₂  > Double bond

Explanation:

<em>What would you predict for the lengths of the bonds in NO₂ relative to NO single bonds and double bonds?</em>

Let's look at the Lewis structures for NO₂. As we can see, it can be represented by 2 resonant structures. We could picture it as N having a single covalent bond with each O and another single covalent bond that is divided by the two bonds. The resulting bond order is 1.5.

As a general rule, the higher the bond order (B.O.), the shorter the bond length. The rank of lengths is:

Single bond (B.O.: 1) > Bond in NO₂ (B.O.: 1.5) > Double bond (B. O.: 2)

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3 years ago
Which one of the following best represents the predicted approximate chemical shift and coupling for the hydrogen(s) indicated w
melomori [17]

Answer:

The answer is quartet 2.40 ppm.

Note: Kindly find an attached image below for the part of the solution to this question

Sources: The image was researched from Course hero platform

Explanation:

Solution

Multiplicity or (n+1) rule:

It helps in determination of multiplicity of an individual proton or individual types of proton which are available in the molecule.

Multiplicity =(n+1)

Thus

The non equivalent protons which are attached from adjacent atom is denoted by n.

Now because there are three non-equivalent protons are present at adjacent carbon of methylene group, hence the multiplicity of methylene hydrogen is given as follows:

The multiplicity will be the same for the two hydrogen's. thus we compute multiplicity only for one  hydrogen atom stated below:

Non- equivalent = 3

Multiplicity = (3 +1)

= 4

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A quartet for 2H indicates that the hydrogen atoms attached from the carbon, which is attached one side from a methyl group and the other side form an atom that have no any hydrogens.

Now due +I effect of carbonyl group, chemical shift value is high for these two hydrogens which is exactly at 2.40 ppm or 2.40 Quartet.

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