KH₂PO₄ hydrolyzes as;
H₂PO₄⁻ + H₂O ↔ H₃PO₄ + OH⁻
Let x amount of H₂PO₄⁻ has reacted with water then,
Kb₁ = [H₃PO₄][OH⁻] / [H₂PO₄⁻]
[H₂PO₄⁻] = 0.8-x M
Kb₁ = x² / (0.8 - x)
Given Ka₁ = 7.5 x 10⁻³
so Kb₁ = 1 x 10⁻¹⁴ / (7.5 x 10⁻³) = 1.33 x 10⁻¹²
From this information:
1.33 x 10⁻¹² = x² / 0.8
x = [OH⁻] = 1.03 x 10⁻⁶ M
pOH = - log (1.03 x 10⁻⁶) = 5.99
pH = 14 - pOH = 14 - 5.99 = 8.01
Answer:
<span>In the addition of hbr to 1-butyne the electrophile in the first step of the mechanism is <u>Hydrogen atom of HBr</u>.
Explanation:
In this reaction first of all HBr approaches the triple bond. A Pi Complex (weak inter-molecular interactions) is formed between the two molecules. And the triple bond attacks the partial positive hydrogen atom creating a negative charge on Bromine along with positive charge on itself (Sigma Complex). In second step the negative Bromide attacks the positive carbon of Butyne.</span>
<span>1. The balanced equation for the reaction between magnesium sulfate and ammonia is MgSO4 + 2NH4OH → (NH4)2SO4 + Mg(OH)2
2. The reaction between magnesium sulfate and ammonia is double displacement.</span>
Friction. Imagine rubbing your hand against a carpet and how it gets hot even though you are pushing it afar. That is friction.
