Answer:
The second one is the answer
Answer:
ΔH°rxn = - 433.1 KJ/mol
Explanation:
- CH4(g) + 4Cl2(g) → CCl4(g) + 4HCl(g)
⇒ ΔH°rxn = 4ΔH°HCl(g) + ΔH°CCl4(g) - 4ΔH°Cl2(g) - ΔH°CH4(g)
∴ ΔH°Cl2(g) = 0 KJ/mol.....pure element in its reference state
∴ ΔH°CCl4(g) = - 138.7 KJ/mol
∴ ΔH°HCl(g) = - 92.3 KJ/mol
∴ ΔH°CH4(g) = - 74.8 KJ/mol
⇒ ΔH°rxn = 4(- 92.3 KJ/mol) + (- 138.7 KJ/mol) - 4(0 KJ/mol) - (- 74.8 KJ/mol)
⇒ ΔH°rxn = - 369.2 KJ/mol - 138.7 KJ/mol - 0 KJ/mol + 74.8 KJ/mol
⇒ ΔH°rxn = - 433.1 KJ/mol
Answer : The activation energy of the reaction is, 
Solution :
The relation between the rate constant the activation energy is,
![\log \frac{K_2}{K_1}=\frac{Ea}{2.303\times R}\times [\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%5Cfrac%7BK_2%7D%7BK_1%7D%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5Ctimes%20%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= initial rate constant = 
= final rate constant = 
= initial temperature = 
= final temperature = 
R = gas constant = 8.314 kJ/moleK
Ea = activation energy
Now put all the given values in the above formula, we get the activation energy.
![\log \frac{8.75\times 10^{-3}L/mole\text{ s}}{4.55\times 10^{-5}L/mole\text{ s}}=\frac{Ea}{2.303\times (8.314kJ/moleK)}\times [\frac{1}{468K}-\frac{1}{531K}]](https://tex.z-dn.net/?f=%5Clog%20%5Cfrac%7B8.75%5Ctimes%2010%5E%7B-3%7DL%2Fmole%5Ctext%7B%20s%7D%7D%7B4.55%5Ctimes%2010%5E%7B-5%7DL%2Fmole%5Ctext%7B%20s%7D%7D%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20%288.314kJ%2FmoleK%29%7D%5Ctimes%20%5B%5Cfrac%7B1%7D%7B468K%7D-%5Cfrac%7B1%7D%7B531K%7D%5D)
Therefore, the activation energy of the reaction is,
Answer:
C. number of particles
Explanation:
Entropy is the measure of disorderliness of a system. Remember that when you dissolve salt in water, you increase the number of particles in the solution. The greater the number of particles in solution, the greater the entropy of the solution system.
Hence dissolution of a salt in water increases the entropy by increasing the number of particles in solution leading to the inequality; Ssolution > Swater + Ssalt.
