Answer:
The steps with correct mechanism are given below:
C
1) CH₄(g) + Cl(g) → CH₃(g) + HCl(g) : This is a slow step.
The rate is given as: R1 = k₁[CH₄][Cl]
2) CH₃(g) + Cl₂(g) → CH₃Cl(g) + Cl(g): This is a fast step.
The rate is given as: Rate = k₂[CH₃][Cl₂]
∴ CH₄(g) + Cl₂(g) → CH₃Cl(g) + HCl(g)
Here, the slowest step will be the rate-determining step.
Because chloride is more reactive than hydrogen.
Silicone is most similar to carbon.
hope this helps; and good luck.
0,35 kmol/m³ = 0,35 mol/dm³ = 0,35 mol/L
175 mL = 0,175 L
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C = n/V
n = 0,35×0,175
n = 0,06125 mol
mCa(NO₃)₂: 40+(14×2)+(16×6) = 164 g/mol
1 mol --------- 164g
0,06125 ---- X
X = 10,045g
To prepare 175 mL of 0,35M solution, add 10,045g of calcium nitrate and add water to a volume of 175ml.