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2 years ago

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According to Boyle’s law, when the pressure of a gas increases at constant temperature, its volume

1 answer:

Leya [2.2K]2 years ago

4 0

Answer:

the volume increases

Explanation:

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Which of the following is an organic compound? carbon monoxide (CO) sodium chloride (NaCl) sulfur oxide (SO) water (H2O)

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If 23.17 g of beryllium (Be) reacts with water at standard temperature and pressure,

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Volume of H2 produced = 57.6576 L

<h3>Further explanation</h3>

Given

23.17 g Be

Required

Volume of H2

Solution

Reaction

Be(s)+H2O(g)→BeO(s)+H2(g)

mol Be :

= 23.17 g : 9 g/mol

= 2.574

From the equation, mol H2 : mol Be = 1 : 1, so mol H2 = 2.574

Volume H2(assumed at STP, 1 mol=22.4 L) :

= 2.574 x 22.4 L

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Consider the following reaction: CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at25 ∘C under these conditions: PCO2PCC

Salsk061 [2.6K]

<u>Answer:</u> The $\Delta G$ for the reaction is 54.6 kJ/mol

<u>Explanation:</u>

For the given balanced chemical equation:

$CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)$

We are given:

$\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol$

To calculate $\Delta G^o_{rxn}$ for the reaction, we use the equation:

$\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]$

For the given equation:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]$

Putting values in above equation, we get:

$\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J$

Conversion factor used = 1 kJ = 1000 J

The expression of $K_p$ for the given reaction:

$K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}$

We are given:

$p_{COCl_2}=0.760atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.180atm$

Putting values in above equation, we get:

$K_p=\frac{(0.760)^2}{0.140\times 0.180}\\\\K_p=22.92$

To calculate the Gibbs free energy of the reaction, we use the equation:

$\Delta G=\Delta G^o+RT\ln K_p$

where,

$\Delta G$ = Gibbs' free energy of the reaction = ?

$\Delta G^o$ = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = $8.314J/K mol$

T = Temperature = $25^oC=[25+273]K=298K$

$K_p$ = equilibrium constant in terms of partial pressure = 22.92

Putting values in above equation, we get:

$\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(22.92))\\\\\Delta G=54659.78J/mol=54.6kJ/mol$

Hence, the $\Delta G$ for the reaction is 54.6 kJ/mol

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2 years ago