Answer : The correct option is, (B) 
Solution :
According to the Graham's law, the rate of effusion of gas is inversely proportional to the square root of the molar mass of gas.
or,
..........(1)
where,
= rate of effusion of unknown gas = 
= rate of effusion of oxygen gas = 
= molar mass of unknown gas = ?
= molar mass of oxygen gas = 32 g/mole
Now put all the given values in the above formula 1, we get:
The unknown gas could be carbon dioxide 
that has approximately 44 g/mole of molar mass.
Thus, the unknown gas could be carbon dioxide
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Hope this helps :)
Answer:
Amount of pyridine required = 0.0316 M
Explanation:
pH of a buffer solution is calculated by using Henderson - Hasselbalch equation.
![pH=pK_a+log\frac{[Conjugate\ base]}{[weak\ acid]}](https://tex.z-dn.net/?f=pH%3DpK_a%2Blog%5Cfrac%7B%5BConjugate%5C%20base%5D%7D%7B%5Bweak%5C%20acid%5D%7D)
Pyridinium is a weak acid and in the presence of its conjugate base, it acts as buffer.
Henderson - Hasselbalch equation for pyridine/pyridinium buffer is as follows:
![pH=pK_a+log\frac{[Py]}{PyH^+]}](https://tex.z-dn.net/?f=pH%3DpK_a%2Blog%5Cfrac%7B%5BPy%5D%7D%7BPyH%5E%2B%5D%7D)
pH = 4.7
(Pyridinium)=0.100 M
Substitute the values in the formula
![pH=pK_a+log\frac{[Py]}{PyH^+]}\\4.7=5.2 log\frac{[Py]}{0.100}](https://tex.z-dn.net/?f=pH%3DpK_a%2Blog%5Cfrac%7B%5BPy%5D%7D%7BPyH%5E%2B%5D%7D%5C%5C4.7%3D5.2%20log%5Cfrac%7B%5BPy%5D%7D%7B0.100%7D)
![4.7-5.2=log\frac{[Py]}{0.100} \\-0.5=log\frac{[Py]}{0.100}\\\frac{[Py]}{0.100}=antilog -0.5\\\frac{[Py]}{0.100}=0.316](https://tex.z-dn.net/?f=4.7-5.2%3Dlog%5Cfrac%7B%5BPy%5D%7D%7B0.100%7D%20%5C%5C-0.5%3Dlog%5Cfrac%7B%5BPy%5D%7D%7B0.100%7D%5C%5C%5Cfrac%7B%5BPy%5D%7D%7B0.100%7D%3Dantilog%20-0.5%5C%5C%5Cfrac%7B%5BPy%5D%7D%7B0.100%7D%3D0.316)
![\frac{[Py]}{0.100} =0.316](https://tex.z-dn.net/?f=%5Cfrac%7B%5BPy%5D%7D%7B0.100%7D%20%3D0.316)
[Py]=0.0316\ M
Amount of pyridine required = 0.0316 M
Answer:
29.232 l
Explanation:
6.023x10^23 mole of nitrogen =22.4 l
7.83×10^23 mole of nitrogen =
22.4/(6.023×10^23)×7.83×10^23
=29.232 l
