Which is the most likely to be reduced
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remember that when the solution is acidic, pH lower than 7. there are extra H+ that the amino acid can take. the basic part of the amino acid takes this extra hydrogen (the nitrogen).
when the pH is higher than 7, basic, there are not much H+ available. the amino acid loses a H+. the acid part of the amino acid loses the H (the carboxylic part).
remember that when the solution is acidic, pH lower than 7. there are extra H+ that the amino acid can take. the basic part of the amino acid takes this extra hydrogen (the nitrogen).
when the pH is higher than 7, basic, there are not much H+ available. the amino acid loses a H+. the acid part of the amino acid loses the H (the carboxylic part).