Answer:
24.24 L
Explanation:
Boyle’s law, also called Mariotte’s law, a relation concerning the compression and expansion of a gas at constant temperature.
This empirical relation, formulated by the physicist Robert Boyle in 1662, states that the pressure (p) of a given quantity of gas varies inversely with its volume (v) at constant temperature; i.e., in equation form, pv = k, a constant.
Real gases obey Boyle’s law at sufficiently low pressures, although the product pv generally decreases slightly at higher pressures, where the gas begins to depart from ideal behaviour.
As, PV = k
P₁ V₁ = P₂ V₂
Given P₁ = 101 KPa
V₁ = 6 L
P₂ = 25 kPa
So, V₂ = P₁ V₁ /P₂ = 101 *6/25 = 24.24 L
Answer:
The reaction will be non spontaneous at these concentrations.
Explanation:
Expression for an equilibrium constant 
:
![K_c=\frac{[Ag^+][Br^-]}{[AgCl]}=\frac{[Ag^+][Br^-]}{1}=[Ag^+][Br^-]](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BAg%5E%2B%5D%5BBr%5E-%5D%7D%7B%5BAgCl%5D%7D%3D%5Cfrac%7B%5BAg%5E%2B%5D%5BBr%5E-%5D%7D%7B1%7D%3D%5BAg%5E%2B%5D%5BBr%5E-%5D)
Solubility product of the reaction:
![K_{sp}=[Ag^+][Br^-]=K_c=7.7\times 10^{-13}](https://tex.z-dn.net/?f=K_%7Bsp%7D%3D%5BAg%5E%2B%5D%5BBr%5E-%5D%3DK_c%3D7.7%5Ctimes%2010%5E%7B-13%7D%20)
Reaction between Gibb's free energy and equilibrium constant if given as:
![\Delta G^o=-2.303\times 8.314 J/K mol\times 298 K\times \log[7.7\times 10^{-13}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo%3D-2.303%5Ctimes%208.314%20J%2FK%20mol%5Ctimes%20298%20K%5Ctimes%20%5Clog%5B7.7%5Ctimes%2010%5E%7B-13%7D%5D)
Gibb's free energy when concentration ![[Ag^+] = 1.0\times 10^{-2} M](https://tex.z-dn.net/?f=%5BAg%5E%2B%5D%20%3D%201.0%5Ctimes%2010%5E%7B-2%7D%20M)
and ![[Br^-] = 1.0\times 10^{-3} M](https://tex.z-dn.net/?f=%5BBr%5E-%5D%20%3D%201.0%5Ctimes%2010%5E%7B-3%7D%20M)
Reaction quotient of an equilibrium = Q
![Q=[Ag^+][Br^-]=1.0\times 10^{-2} M\times 1.0\times 10^{-3} M=1.0\times 10^{-5}](https://tex.z-dn.net/?f=Q%3D%5BAg%5E%2B%5D%5BBr%5E-%5D%3D1.0%5Ctimes%2010%5E%7B-2%7D%20M%5Ctimes%201.0%5Ctimes%2010%5E%7B-3%7D%20M%3D1.0%5Ctimes%2010%5E%7B-5%7D)
![\Delta G=69.117 kJ/mol+(2.303\times 8.314 Joule/mol K\times 298 K\times \log[1.0\times 10^{-5}])](https://tex.z-dn.net/?f=%5CDelta%20G%3D69.117%20kJ%2Fmol%2B%282.303%5Ctimes%208.314%20Joule%2Fmol%20K%5Ctimes%20298%20K%5Ctimes%20%5Clog%5B1.0%5Ctimes%2010%5E%7B-5%7D%5D%29)
- For reaction to spontaneous reaction:
. - For reaction to non spontaneous reaction:
.
Since ,the value of Gibbs free energy is greater than zero which means reaction will be non spontaneous at these concentrations
Answer:
223.6539
Explanation:
1 mole is equal to 1 moles KCl, or 74.5513 grams
