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zmey [24]
3 years ago
6

Phentyfloroform contains 57.54% C, 3.45% H, and 39.01% F. What is its empirical formula?​

Chemistry
1 answer:
kap26 [50]3 years ago
6 0

Answer:

Empirical formula is C₇H₅F₃

Explanation:

Given data:

Percentage of hydrogen = 3.45%

Percentage of carbon = 57.54%

Percentage of fluorine = 39.01%

Empirical formula = ?

Solution:

Number of gram atoms of H = 3.45 / 1.01 = 3.42

Number of gram atoms of F = 39.01 / 18.99 = 2.05

Number of gram atoms of C = 57.54/ 12.01 = 4.79

Atomic ratio:

            C                      :        H                :         F

           4.79/2.05         :     3.42/2.05      :       2.05/2.05

            2.34                 :        1.67                  :        1

C : H : F = 3(2.34 : 1.67 : 1 )

Empirical formula is C₇H₅F₃.

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Explanation :

First we have to calculate the moles of C_3H_5N_3O_9

\text{Moles of }C_3H_5N_3O_9=\frac{\text{Given mass }C_3H_5N_3O_9}{\text{Molar mass }C_3H_5N_3O_9}=\frac{227g}{227g/mol}=1mol

Now we have to calculate the moles of CO_2,O_2,N_2\text{ and }H_2O

The balanced chemical reaction is:

4C_3H_5N_3O_9(l)\rightarrow 12CO_2(g)+O_2(g)+6N_2(g)+10H_2O(g)

From the balanced chemical reaction we conclude that,

As, 4 moles of C_3H_5N_3O_9 react to give 12 moles of CO_2

So, 1 moles of C_3H_5N_3O_9 react to give \frac{12}{4}=3 moles of CO_2

and,

As, 4 moles of C_3H_5N_3O_9 react to give 1 moles of O_2

So, 1 moles of C_3H_5N_3O_9 react to give \frac{1}{4}=0.25 moles of O_2

and,

As, 4 moles of C_3H_5N_3O_9 react to give 6 moles of N_2

So, 1 moles of C_3H_5N_3O_9 react to give \frac{6}{4}=1.5 moles of N_2

and,

As, 4 moles of C_3H_5N_3O_9 react to give 10 moles of H_2O

So, 1 moles of C_3H_5N_3O_9 react to give \frac{10}{4}=2.5 moles of H_2O

Now we have to calculate the mole fraction of water.

\text{Mole fraction of }H_2O=\frac{\text{Moles of }H_2O}{\text{Moles of }H_2O+\text{Moles of }CO_2+\text{Moles of }O_2+\text{Moles of }N_2}

\text{Mole fraction of }H_2O=\frac{2.5}{2.5+3+0.25+1.5}=0.345

Now we have to calculate the partial pressure of the water vapor.

According to the Raoult's law,

p_{H_2O}=X_{H_2O}\times p_T

where,

p_{H_2O} = partial pressure of water vapor gas  = ?

p_T = total pressure of gas  = 58 atm

X_{H_2O} = mole fraction of water vapor gas  = 0.345

Now put all the given values in the above formula, we get:

p_{H_2O}=X_{H_2O}\times p_T

p_{H_2O}=0.345\times 58atm=20.01atm

Therefore, the partial pressure of the water vapor is, 20.01 atm

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