Balanced equation(That should be NaClO_3)

Remember that it's a ionic equation not general equation
So
We have to balance it accordingly
Ionic compound are those compounds which are made up of ions. The ion which has tendency to loose electrons is said to cation (positive charge) such as metals whereas ion which has tendency to gain electrons is said to anion (negative charge) such as non-metals.
Calcium nitrate is quite soluble in water due to very low lattice enthalpy in comparison to other ionic compound. With lower lattice enthalpy, less energy is required for the dissociation of calcium nitrate and it get dissolves in water than other three compounds. Moreover, hydration energy is higher for calcium nitrate which make its solubility higher in water than other ionic species.
Thus,
is correct answer.
Just for more clarification, lowercase k is the rate constant. Uppercase K is the equilibrium constant. You can actually use k to find K (equilibrium constant). K=k/k' This means that the equilibrium constant is the rate constant of the forward reaction divided by the rate constant of the reverse reaction
We can calculate the final temperature from this formula :
when Tf = (V1* T1) +(V2* T2) / (V1+ V2)
when V1 is the first volume of water = 5 L
and V2 is the second volume of water = 60 L
and T1 is the first temperature of water in Kelvin = 80 °C +273 = 353 K
and T2 is the second temperature of water in Kelvin = 30°C + 273= 303 K
and Tf is the final temperature of water in Kelvin
so, by substitution:
Tf = (5 L * 353 K ) + ( 60 L * 303 K) / ( 5 L + 60 L)
= 1765 + 18180 / 65 L
= 306 K
= 306 -273 = 33° C