Answer: The given statement is TRUE.
Explanation:
An equilibrium reaction is one in which rate of forward reaction is equal to the rate of backward reaction.
Equilibrium constant is defined as the ratio of the product of the concentration of products to the product of the concentration of reactants each raised to their stochiometric coefficient.
For example for the given equilibrium reaction;
![K_{eq}=\frac{[H_2]^2[O_2]}{[H_2O]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BH_2%5D%5E2%5BO_2%5D%7D%7B%5BH_2O%5D%5E2%7D)
Thus the given statement that in calculating the equilibrium constant for a reaction, the coefficients of the chemical equation are used as exponents for the factors in the equilibrium expression is True.
1.785714286 moles
The number of moles (n) for nitrogen is: [ n=50.0÷28.0 ] = 1.785714286 moles.
Chloroacetic acid is stronger than acetic acid because of the electron-withdrawing effect of chlorine. This effect is caused by the electronegativity.
1) Chemical reaction
HCl + NaOH ---> NaCl + H2O
25.0 ml
0.150 M 0.250M
2) 50% completion => 0.025 l * 0.150 M * (1/2) = 0.001875 mol HCl consumed and 0.001875 mol HCl in solution
0.001875 mol HCl => 0.001875 mol H(+)
Volume = Volume of HCl solution + Volumen of NaOH solution added
Volume of HCl solution = 0.0250 l
Volume of NaOH = n / M = 0.001875 mol / 0.250M = 0.0075 l
Total volume = 0.0250 l + 0.0075 l = 0.0325 l
[H+] = 0.001875 mol / 0.0325 l = 0.05769 M
pH = - log [H+] = - log (0.05769) = 1.23
Answer: 1.23
3) Equivalence point
0.02500 l * 0.150 M = 0.250M * V
=> V = 0.02500 * 0.150 / 0.250 = 0.015 l
4) 1.00 ml NaOH added beyond the equivalence point
1.00 ml * 1 l / 1000 ml * 0.250 M = 0.00025 mol NaOH in excess
0.00025 mol NaOH = 0.00025 mol OH-
Volume of the solution = 0.02500 l + 0.015 l + 1.00/1000 l = 0.041 l
[OH-] = 0.00025 mol / 0.041 l = 0.00610 M
pOH = - log (0.00610) = 2.21
pH + pOH = 14 => pH = 14 - pOH = 14 - 2.21 = 11.76
Answer: 11.76
Answer:
The entropy change for a real, irreversible process is equal to <u>zero.</u>
The correct option is<u> 'c'.</u>
Explanation:
<u>Lets look around all the given options -:</u>
(a) the entropy change for a theoretical reversible process with the same initial and final states , since the entropy change is equal and opposite in reversible process , thus this option in not correct.
(b) equal to the entropy change for the same process performed reversibly ONLY if the process can be reversed at all. Since , the change is same as well as opposite too . Therefore , this statement is also not true .
(c) zero. This option is true because We generate more entropy in an irreversible process. Because no heat moves into or out of the surroundings during the procedure, the entropy change of the surroundings is zero.
(d) impossible to tell. This option is invalid , thus incorrect .
<u>Hence , the correct option is 'c' that is zero.</u>
