Answer:
91.7 kJ
Explanation:
Step 1: Given data
- Mass of ammonia (m): 66.7 g
- Molar heat of vaporization of ammonia (ΔH°vap): 23.4 kJ/mol
Step 2: Calculate the moles (n) corresponding to 66.7 g of ammonia
The molar mass of ammonia is 17.03 g/mol.
66.7 g × 1 mol/17.03 g = 3.92 mol
Step 3: Calculate the heat (Q) required to boil 3.92 moles of ammonia
We will use the following expression.
Q = ΔH°vap × n
Q = 23.4 kJ/mol × 3.92 mol = 91.7 kJ
Answer:
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Missing in your question Ka2 =6.3x10^-8
From this reaction:
H2SO3 + H2O ↔ H3O+ + HSO3-
by using the ICE table :
H2SO3 ↔ H3O + HSO3-
intial 0.6 0 0
change -X +X +X
Equ (0.6-X) X X
when Ka1 = [H3O+][HSO3-]/[H2SO3]
So by substitution:
1.5X10^-2 = (X*X) / (0.6-X) by solving this equation for X
∴ X = 0.088
∴[H2SO3] = 0.6 - 0.088 = 0.512
[HSO3-] = [H3O+] = 0.088
by using the ICE table 2:
HSO3- ↔ H3O + SO3-
initial 0.088 0.088 0
change -X +X +X
Equ (0.088-X) (0.088+X) X
Ka2= [H3O+] [SO3-] / [HSO3-]
we can assume [HSO3-] = 0.088 as the value of Ka2 is very small
6.3x10^-8 = (0.088+X)*X / 0.088
X^2 +0.088 X - 5.5x10^-9= 0 by solving this equation for X
∴X= 6.3x10^-8
∴[H3O+] = 0.088 + 6.3x10^-8
= 0.088 m ( because X is so small)
∴PH= -㏒[H3O+]
= -㏒ 0.088 = 1.06
Using p1v1/t1=p2v2/t2
p1=50
p2=225
v1=400ml
v2=?
t1=-20=253k
t2=60=333k
50x400/253=225xv2/333
7.9=0.7xv2
v2=7.9/0.7
v2=11.3ml
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