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Andreas93 [3]
3 years ago
6

Butane C4H10 (g),(Hf = –125.7), combusts in the presence of oxygen to form CO2 (g) (Delta.Hf = –393.5 kJ/mol), and H2O(g) (Delta

.Hf = –241.82) in the reaction: 2 upper C subscript 4 upper H subscript 10 (g) plus 13 upper O subscript 2 (g) right arrow 8 upper C upper O subscript 2 plus 10 upper H subscript 2 upper O (g). What is the enthalpy of combustion, per mole, of butane? Use Delta H r x n equals the sum of delta H f of all the products minus the sum of delta H f of all the reactants.
Chemistry
1 answer:
shusha [124]3 years ago
3 0

Answer: The enthalpy of combustion, per mole, of butane is -2657.4 kJ

Explanation:

The balanced chemical reaction is,

2C_4H_{10}(g)+13O_2(g)\rightarrow 8CO_2(g)+10H_2O(g)

The expression for enthalpy change is,

\Delta H=[n\times H_f_{products}]-[n\times H_f_{reactants}]

Putting the values we get :

\Delta H=[8\times H_f_{CO_2}+10\times H_f_{H_2O}]-[2\times H_f_{C_4H_{10}+13\times H_f_{O_2}}]

\Delta H=[(8\times -393.5)+(10\times -241.82)]-[(2\times -125.7)+(13\times 0)]

\Delta H=-5314.8kJ

2 moles of butane releases heat = 5314.8 kJ

1 mole of butane release heat = \frac{5314.8}{2}\times 1=2657.4kJ

Thus enthalpy of combustion per mole of butane is -2657.4 kJ

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At an elevated temperature, Kp=4.2 x 10^-9 for the reaction 2HBr (g)---> +H2(g) + Br2 (g). If the initial partial pressures o
Damm [24]

Answer : The partial pressure of H_2 at equilibrium is, 1.0 × 10⁻⁶

Explanation :

The partial pressure of HBr = 1.0\times 10^{-2}atm

The partial pressure of H_2 = 2.0\times 10^{-4}atm

The partial pressure of Br_2 = 2.0\times 10^{-4}atm

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The balanced equilibrium reaction is,

                                2HBr(g)\rightleftharpoons H_2(g)+Br_2(g)

Initial pressure    1.0×10⁻²       2.0×10⁻⁴      2.0×10⁻⁴

At eqm.            (1.0×10⁻²-2p)   (2.0×10⁻⁴+p)  (2.0×10⁻⁴+p)

The expression of equilibrium constant K_p for the reaction will be:

K_p=\frac{(p_{H_2})(p_{Br_2})}{(p_{HBr})^2}

Now put all the values in this expression, we get :

4.2\times 10^{-9}=\frac{(2.0\times 10^{-4}+p)(2.0\times 10^{-4}+p)}{(1.0\times 10^{-2}-2p)^2}

p=-1.99\times 10^{-4}

The partial pressure of H_2 at equilibrium = (2.0×10⁻⁴+(-1.99×10⁻⁴) )= 1.0 × 10⁻⁶

Therefore, the partial pressure of H_2 at equilibrium is, 1.0 × 10⁻⁶

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3 years ago
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D.
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2Na                        2Na
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2F                           2Br

This is balanced.
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