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miskamm [114]
3 years ago
6

Calculate [H3O+] and [OH−] for each of the following solutions at 25 ∘C given the pH. pH= 2.89

Chemistry
1 answer:
dimaraw [331]3 years ago
6 0

Answer: The value of [H_{3}O^{+}] is 0.0012 M and [OH^{-}] is 1.02 \times 10^{-14}.

Explanation:

pH is the negative logarithm of concentration of hydrogen ion.

It is given that pH is 2.89. So, the value of concentration of hydrogen ions is calculated as follows.

pH = - log [H^{+}]\\2.89 = - log [H^{+}]\\conc. H^{+} = 0.0012 M

The relation between pH and pOH value is as follows.

pH + pOH = 14

0.0012 + pOH = 14

pOH = 14 - 0.0012 = 13.99

Now, pOH is the negative logarithm of concentration of hydroxide ions.

Hence, [OH^{-}] is calculated as follows.

pOH = - log [OH^{-}]\\13.99 = - log [OH^{-}]\\conc. OH^{-} = 1.02 \times 10^{-14} M

Thus, we can conclude that the value of [H_{3}O^{+}] is 0.0012 M and [OH^{-}] is 1.02 \times 10^{-14}.

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Explanation:

According to Buoyance equation,

          m = [m' \times \frac{1 - \frac{d_{a}}{d_{w}}}{1 - \frac{d_{a}}{d}}]

where,      m = true mass

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Now, putting all the given values into the above formula and calculate the true mass as follows.

      m = [m' \times \frac{1 - \frac{d_{a}}{d_{w}}}{1 - \frac{d_{a}}{d}}]    

          = [17.320 g \times \frac{1 - \frac{0.0012 g/ml}{7.5 g/ml}}{1 - \frac{0.0012 g/ml}{0.7025}}]

          = 17.320 g \times 0.999850                

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The decomposition of hydrogen peroxide was studied, and the following data were obtained at a particular temperature: Time (s) (
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Answer:

Part a: The rate of the equation for 1st order reaction is given as  Rate=k[H_2O_2]

Part b: The integrated Rate Law is given as [H_2O_2]=[H_2O_2]_0 e^{-kt}

Part c: The value of rate constant is 7.8592 \times 10^{-4} s^{-1}

Part d: Concentration after 4000 s is 0.043 M.

Explanation:

By plotting the relation between the natural log of concentration of H_2O_2, the graph forms a straight line as indicated in the figure attached. This indicates that the reaction is of 1st order.

Part a

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The rate of the equation for 1st order reaction is given as

Rate=k[H_2O_2]

Part b

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The integrated Rate Law is given as

[H_2O_2]=[H_2O_2]_0 e^{-kt}

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Value of the rate constant is given by using the relation between 1st two observations i.e.

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Concentration after 4000 s is given as

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Concentration after 4000 s is 0.043 M.

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