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Explanation:
According to Buoyance equation,
m = ![[m' \times \frac{1 - \frac{d_{a}}{d_{w}}}{1 - \frac{d_{a}}{d}}]](https://tex.z-dn.net/?f=%5Bm%27%20%5Ctimes%20%5Cfrac%7B1%20-%20%5Cfrac%7Bd_%7Ba%7D%7D%7Bd_%7Bw%7D%7D%7D%7B1%20-%20%5Cfrac%7Bd_%7Ba%7D%7D%7Bd%7D%7D%5D)
where, m = true mass
m' = mass read from the balance = 17.320 g
= density of air = 0.0012 g/ml
= density of the balance = 7.5 g/ml
d = density of liquid octane = 0.7025 g/ml
Now, putting all the given values into the above formula and calculate the true mass as follows.
m =
= ![[17.320 g \times \frac{1 - \frac{0.0012 g/ml}{7.5 g/ml}}{1 - \frac{0.0012 g/ml}{0.7025}}]](https://tex.z-dn.net/?f=%5B17.320%20g%20%5Ctimes%20%5Cfrac%7B1%20-%20%5Cfrac%7B0.0012%20g%2Fml%7D%7B7.5%20g%2Fml%7D%7D%7B1%20-%20%5Cfrac%7B0.0012%20g%2Fml%7D%7B0.7025%7D%7D%5D)
=
= 17.317 g
Thus, we can conclude that the true mass of octane is 17.317 g.
Answer:
Part a: The rate of the equation for 1st order reaction is given as ![Rate=k[H_2O_2]](https://tex.z-dn.net/?f=Rate%3Dk%5BH_2O_2%5D)
Part b: The integrated Rate Law is given as ![[H_2O_2]=[H_2O_2]_0 e^{-kt}](https://tex.z-dn.net/?f=%5BH_2O_2%5D%3D%5BH_2O_2%5D_0%20e%5E%7B-kt%7D)
Part c: The value of rate constant is 
Part d: Concentration after 4000 s is 0.043 M.
Explanation:
By plotting the relation between the natural log of concentration of
, the graph forms a straight line as indicated in the figure attached. This indicates that the reaction is of 1st order.
Part a
Rate Law
The rate of the equation for 1st order reaction is given as
![Rate=k[H_2O_2]](https://tex.z-dn.net/?f=Rate%3Dk%5BH_2O_2%5D)
Part b
Integrated Rate Law
The integrated Rate Law is given as
![[H_2O_2]=[H_2O_2]_0 e^{-kt}](https://tex.z-dn.net/?f=%5BH_2O_2%5D%3D%5BH_2O_2%5D_0%20e%5E%7B-kt%7D)
Part c
Value of the Rate Constant
Value of the rate constant is given by using the relation between 1st two observations i.e.
t1=0, M1=1.00
t2=120 s , M2=0.91
So k is calculated as

The value of rate constant is 
Part d
Concentration after 4000 s is given as

Concentration after 4000 s is 0.043 M.
Because the reaction occurs between a metal and non metal
CL=2,8,7
C