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Answer:
Draw structures corresponding to the following IUPAC names:(a) (Z)-2-Ethyl-2-buten-1-ol (b) 3-Cyclohexen-1-ol(c) trans-3-Chlorocycloheptanol (d) 1,4-Pentanediol(e) 2,6-Dimethylphenol (f ) o-(2-Hydroxyethyl)phenol
Explanation:
According to IUPAC rules, the name of a compound is:
Prefix+root word+suffix
1) Select the longest carbon chain and it gives the root word.
2) The substituents give the prefix.
3) The functional group gives the secondary suffix and the type of carbon chain gives the primary suffix.
The structure of the given compounds are shown below:
0.116 V is the e value for the oxidation of cytochrome c by the cue redox center in complex iv when the ratio of cyst c (fe3 ) /cyst c (fe2 ) is 20 and the ratio of cue (cu2 )/cue (cu ) is 3.
<h3>
Explain the process of oxidation of cytochrome c.</h3>
When cytochrome c is oxidized by mitochondrial cytochrome oxidase (COX), it attaches to Apaf-1 to produce the apoptozole, which activates pro-caspase-9 and causes cell death. Cyst can be created from cytosolic cytochrome c. In the IMS, oxidized cytochrome c can scavenge superoxide without converting it into H2O2, a process that happens naturally but is accelerated by SOD. The benefit of scavenging superoxide independently of H2O2 synthesis is reducing the possibility of hydroxyl radical generation via the Fenton reaction.
To learn more about the oxidation of cytochrome c, visit:
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Answer:
The answer to your question is below
Explanation:
5) Fe₂O₃(s) + 3H₂O ⇒ 2Fe(OH)₃ (ac) Synthesis reaction
6) 2C₄H₁₀(g) + 13O₂(g) ⇒ 8CO₂ (g) + 10H₂O Combustion reaction
7) 2NO₂ (g) ⇒ 2O₂ (g) + N₂ (g) Decomposition reaction
8) H₃P (g) + 2O₂ (g) ⇒ PO (g) + 3H₂O Single replacement reaction
<span>1 trial : you have nothing to compare the result with - you don't know if it's a mistake.
2 trials : you can compare results - if very different, one may have gone wrong, but which one?
3 trials : if 2 results are close and 3rd far away, 3rd probably unreliable and can be rejected.
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First calculate the enthalpy of fusion. M, C and m,c = mass and
specific heat of calorimeter and water; n, L = mass and heat of fusion
of ice; T = temperature fall.
L = (mc+MC)T/n.
c=4.18 J/gK. I assume calorimeter was copper, so C=0.385 J/gK.
1. M = 409g, m = 45g. T = 22c, n = 14g
L = (45*4.18+409*0.385)*22/14 = 543.0 J/g.
2. M = 409g, m = 49g, T = 20c, n = 13g
L = (49*4.18+409*0.385)*20/13 = 557.4 J/g.
3. M = 409g, m = 54g, T = 20c, n = 14g
L = (54*4.18+409*0.385)*20/14 = 547.4 J/g.
(i) Estimate error in L from spread of 3 results.
Average L = 549.3 J/g.
average of squared differences (variance) = (6.236^2+8.095^2+1.859^2)/3 = 35.96
standard deviation = 5.9964
standard error = SD/(N-1) = 5.9964/2 = 3 J/g approx.
% error = 3/547 x 100% = 0.5%.
(ii) Estimate error in L from accuracy of measurements:
error in masses = +/-0.5g
error in T = +/-0.5c
For Trial 3
M = 409g, error = 0.5g
m = 463-409, error = sqrt(0.5^2+0.5^2) = 0.5*sqrt(2)
n =(516-463)-(448-409)=14, error = 0.5*sqrt(4) = 1.0g
K = (mc+MC)=383, error = sqrt[2*(0.5*4.18)^2+(0.5*0.385)^2] = 2.962
L = K*T/n
% errors are
K: 3/383 x 100% = 0.77
T: 0.5/20 x 100% = 2.5
n: 1.0/14 x 100% = 7.14
% errors in K and T are << error in n, so we can ignore them.
% error in L = same as in n = 7% x 547.4 = 40 (always round final error to 1 sig fig).
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The result is (i) L= 549 +/- 3 J/g or (ii) L = 550 +/- 40 J/g.
Both are very far above accepted figure of 334 J/g, so there is at least
one systematic error in the experiment or the calculations.
eg calorimeter may not be copper, so C is not 0.385 J/gK. (If it was
polystyrene, which absorbs/ transmits little heat, the effective value
of C would be very low, reducing L.)
Using +/- 40 is probably best (more cautious).
However, the spread in the actual results is much smaller; try to explain this discrepancy - eg
* measurements were "fiddled" to get better results; other Trials were made but only best 3 were chosen.
* measurements were more accurate than I assumed (eg masses to nearest 0.1g but rounded to 1g when written down).
Other sources of error:
L=(mc+MC)T/n is too high, so n (ice melted) may be too small, or T (temp fall) too high - why?
* it is suspicious that all final temperatures were 0c - was this
actually measured or just guessed? a higher final temp would reduce L.
* we have assumed initial and final temperature of ice was 0c, it may
actually have been colder, so less ice would melt - this could explain
small values of n
* some water might have been left in container when unmelted ice was
weighed (eg clinging to ice) - again this could explain small n;
* poor insulation - heat gained from surroundings, melting more ice,
increasing n - but this would reduce measured L below 334 J/g not
increase it.
* calorimeter still cold from last trial when next one started, not
given time to reach same temperature as water - this would reduce n.
Hope This Helps :)
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