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Sedbober [7]
3 years ago
11

Write a balanced half-reaction for the oxidation of gaseous nitric oxide NO to nitrate ion NO−3 in acidic aqueous solution. Be s

ure to add physical state symbols where appropriate.
Chemistry
1 answer:
crimeas [40]3 years ago
3 0

Answer:

2H_2O(l)+NO(g)\rightarrow NO_3^-(aq) +4H^+(aq)+3e^-

Explanation:

Hello there!

In this case, according to the given information, it turns out possible to set up the initial version of the half-reaction as follows:

NO\rightarrow NO_3^-

Now, we assign the oxidation numbers to both nitrogen atoms:

N^{2+}O\rightarrow N^{5+}O_3^-

It means three electrons are carried, two water molecules are needed on the left side in order to balance the oxygen atoms and consequently four hydronium ions to balance hydrogen atoms in acidic media:

2H_2O(l)+NO(g)\rightarrow NO_3^-(aq) +4H^+(aq)+3e^-

Regards!

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      <em><u>calculation</u></em>

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        that is  moles for Li,Cl,O and that of H2O

  • moles = % composition/ molar mass

       For Li = 4.330/ 6.94 g/mol=  0.624 moles

             Cl=22.10/35.5=0.623  moles

           39.89/16 g/mol =2.493  moles

           H20=  33.69/18 g/mol=  1.872  moles

  • find  the mole ratio  by  dividing each moles by smallest number of mole ( 0.624 moles)

        that  is  for  Li= 0.624/0.623=  1

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<h3>Therefore the formula=LiClO4.3H2O</h3><h3 />
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see explanation below

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In order to do this, we need to write the reaction and do the mechanism. The nucleophylic site will be the site where the nucleophyle attacks to form the product. In this case the site is the carbon next to the bromine. In this place the Oxigen which is the nucleophyle goes. The electrophyle is the site where one atom substract to complete it's charges. In this case, the electrophyle is usually the hydrogen, so the site will be next to the oxygen after the nucleophyle attack.

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