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anygoal [31]
3 years ago
15

Determine whether the stopcock should be completely open, partially open, or completely closed for each activity involved with t

itration.
Close to the calculated endpoint of a titration ________
At the beginning of a titration _______
Filling the buret with titrant ________
Conditioning the buret with titrant _______
Chemistry
1 answer:
densk [106]3 years ago
3 0

Answer:

Close to the calculated endpoint of a titration - <u>Partially open</u>

At the beginning of a titration - <u>Completely open</u>

Filling the buret with titrant - <u>Completely closed</u>

Conditioning the buret with the titrant - <u>Completely closed</u>

Explanation:

'Titration' is depicted as the process under which the concentration of some substances in a solution is determined by adding measured amounts of some other substance until a rection is displayed to be complete.

As per the question, the stopcock would remain completely open when the process of titration starts. After the buret is successfully placed, the titrant is carefully put through the buret in the stopcock which is entirely closed. Thereafter, when the titrant and the buret are conditioned, the stopcock must remain closed for correct results. Then, when the process is near the estimated end-point and the solution begins to turn its color, the stopcock would be slightly open before the reading of the endpoint for adding the drops of titrant for final observation.

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What is the standard electrode potential for a galvanic cell constructed in the appropriate way from these two half-cells?
____ [38]

E

θ

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=

+

2.115

l

V

Cathode

Mg

2

+

/

Mg

Anode

Ni

2

+

/

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Explanation:

Look up the reduction potential for each cell in question on a table of standard electrode potential like this one from Chemistry LibreTexts. [1]

Mg

2

+

(

a

q

)

+

2

l

e

−

→

Mg

(

s

)

−

E

θ

=

−

2.372

l

V

Ni

2

+

(

a

q

)

+

2

l

e

−

→

Ni

(

s

)

−

E

θ

=

−

0.257

l

V

The standard reduction potential

E

θ

resembles the electrode's strength as an oxidizing agent and equivalently its tendency to get reduced. The reduction potential of a Platinum-Hydrogen Electrode under standard conditions (

298

l

K

,

1.00

l

kPa

) is defined as

0

l

V

for reference. [2]

A cell with a high reduction potential indicates a strong oxidizing agent- vice versa for a cell with low reduction potentials.

Two half cells connected with an external circuit and a salt bridge make a galvanic cell; the half-cell with the higher

E

θ

and thus higher likelihood to be reduced will experience reduction and act as the cathode, whereas the half-cell with a lower

E

θ

will experience oxidation and act the anode.

E

θ

(

Ni

2

+

/

Ni

)

>

E

θ

(

Mg

2

+

/

Mg

)

Therefore in this galvanic cell, the

Ni

2

+

/

Ni

half-cell will experience reduction and act as the cathode and the

Mg

2

+

/

Mg

the anode.

The standard cell potential of a galvanic cell equals the standard reduction potential of the cathode minus that of the anode. That is:

E

θ

cell

=

E

θ

(

Cathode

)

−

E

θ

(

Anode

)

E

θ

cell

=

−

0.257

−

(

−

2.372

)

E

θ

cell

=

+

2.115

Indicating that connecting the two cells will generate a potential difference of

+

2.115

l

V

across the two cells.

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