Answer:
Explanation:
Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
slow
fast
To determine the net chemical equation, we will simply add the above two equations, we get:
Order with respect to is 1 and Order with respect to
is 2.
Thus the rate law will be:
Answer:
r= 0.9949 (For 15,000)
r=0.995 (For 19,000)
Explanation:
We know that
Molecular weight of hexamethylene diamine = 116.21 g/mol
Molecular weight of adipic acid = 146.14 g/mol
Molecular weight of water = 18.016 g/mol
As we know that when adipic acid and hexamethylene diamine react then nylon 6, 6 comes out as the final product and release 2 molecule of water.
So
So
Mo= 226.32/2 =113.16 g/mol
Given that
Mn= 15,000 g/mol
So
15,000 = Xn x 113.16
Xn = 132.55
Now by using Carothers equation we know that
By calculating we get
r= 0.9949
For 19,000
19,000 = Xn x 113.16
Xn = 167.99
By calculating in same process given above we get
r=0.995
Answer:
Check the explanation
Explanation:
Answer – Given, acid and there are three Ka values
The transformation of is the second dissociation, so we need to use the Ka2 = 6.2x10-8 in the Henderson-Hasselbalch equation.
Mass of KH2PO4 = 22.0 g , mass of Na2HPO4 = 32.0 g , volume = 1.00 L
First we need to calculate moles of each
Moles of KH2PO4 = 22.0 g / 136.08 g.mol-1
= 0.162 moles
Moles of Na2HPO4 = 32.0 g /141.96 g.mol-1
= 0.225 moles
[H2PO4-] = 0.162 moles / 1.00 L = 0.162 M
[HPO42-] = 0.225 moles / 1.00 L = 0.225 M
Now we need to calculate the pKa2
pKa2 = -log Ka
= -log 6.2x10-8
= 7.21
We know Henderson-Hasselbalch equation
pH = pKa + log [conjugate base] / [acid]
pH = 7.21 + log 0.225 / 0.162
= 7.35
The pH of a buffer solution obtained by dissolving 22.0 g of KH2PO4 and 32.0 g of Na2HPO4 in water and then diluting to 1.00 L is 7.35