Here we will use the general formula of Nernst equation:
Ecell = E°Cell - [(RT/nF)] *㏑Q
when E cell is cell potential at non - standard state conditions
E°Cell is standard state cell potential = - 0.87 V
and R is a constant = 8.314 J/mol K
and T is the temperature in Kelvin = 73 + 273 = 346 K
and F is Faraday's constant = 96485 C/mole
and n is the number of moles of electron transferred in the reaction=2
and Q is the reaction quotient for the reaction
SO42-2(aq) + 4H+(aq) +2Br-(aq) ↔ Br2(aq) + SO2(g) +2H2O(l)
so by substitution :
0 = -0.87 - [(8.314*346K)/(2* 96485)*㏑Q → solve for Q
∴ Q = 4.5 x 10^-26
Both have a continuous light spectra the fluorescent source makes a spectra with more intense bands of mercury
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Answer:
Yes Concurred,but where is the question
Hbro dissociate as follows
HBro---> H+ + BrO-
Ka= (H+)(BrO-) / HBro
PH = -log (H+)
therefore (H+) = 10^-4.48= 3.31 x10^-5
ka is therefore= ( 3.31 x 10^-5)^2/0.55=1.99 x10^-9
2 SO₃ --> 2 SO₂ + O₂
I 12 0 0
C -2x +2x +x
---------------------------------------------
E 12-2x 2x x
Since the moles of SO₂ at equilibrium is 3 mol, 2x = 3. Then, x = 1.5 mol. So, the amounts at equilibrium is:
SO₃: 12 - 2(1.5) = 9
SO₂: 2(1.5) = 3
O₂: 1.5
The formula for K basing on the stoichiometric reaction is:
K = [SO₂]²[O₂]/[SO₃]²
where the unit used is conc in mol/L.
K = [3 mol/3 L]²[1.5 mol/3 L]/[9 mol/3 L]²
<em>K = 0.0556</em>
