Answer: polar molecule.
Explanation:
The boiling point is the temperature at which the vapor pressure of a liquid equals the external pressure surrounding the liquid. The boiling point is dependent on the type of forces present.
Iodine monochloride (ICl) is a polar molecule due to the difference in electronegativities of iodine and chlorine. Thus the molecules are bonded by strong dipole dipole forces. Thus a higher temperature is needed to generate enough vapor pressure.
Bromine 
is a non polar molecule as there is no electronegativity difference between two bromine atoms. The molecules are bonded by weak vanderwaal forces and thus has low boiling point.
Answer:
(A) 0.129 M
(B) 0.237 M
Explanation:
(A) The reaction between potassium hydrogen phthalate and barium hydroxide is:
- 2HA + Ba(OH)₂ → BaA₂ + 2H₂O
Where A⁻ is the respective anion of the monoprotic acid (KC₈H₄O₄⁻).
We <u>convert mass of phthalate to moles</u>, using its molar mass:
- 0.978 g ÷ 156 g/mol = 9.27x10⁻³ mol = 9.27 mmol
Now we <u>convert mmol of HA to mmol of Ba(OH)₂</u>:
- 9.27 mmol HA *
= 6.64 mmol Ba(OH)₂
Finally we calculate the molarity of the Ba(OH)₂ solution:
- 6.64 mmol / 35.8 mL = 0.129 M
(B) The reaction between Ba(OH)₂ and HCl is:
- 2HCl + Ba(OH)₂ → BaCl₂ + 2H₂O
So<u> the moles of HCl that reacted </u>are:
- 17.1 mL * 0.129 M *
= 4.41 mmol HCl
And the <u>molarity of the HCl solution is</u>:
- 4.41 mmol / 18.6 mL = 0.237 M
Answer:
a) Limiting: sulfur. Excess: aluminium.
b) 1.56g Al₂S₃.
c) 0.72g Al
Explanation:
Hello,
In this case, the initial mass of both aluminium and sulfur are missing, therefore, one could assume they are 1.00 g for each one. Thus, by considering the undergoing chemical reaction turns out:
a) Thus, considering the assumed mass (which could be changed based on the one you are given), the limiting reagent is identified as shown below:
Thereby, since there 1.00g of aluminium will consume 0.0554 mol of sulfur but there are just 0.0156 mol available, the limiting reagent is sulfur and the excess reagent is aluminium.
b) By stoichiometry, the produced grams of aluminium sulfide are:
c) The leftover is computed as follows:
NOTE: Remember I assumed the quantities, they could change based on those you are given, so the results might be different, but the procedure is quite the same.
Best regards.
To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:
I remember the following electronegativities most because they are fairly patterned:
EN
H
=
2.1
EN
C
=
2.5
EN
N
=
3.0
EN
O
=
3.5
EN
F
=
4.0
EN
Cl
=
3.5
Notice how carbon through fluorine go in increments of
~
0.5
. I believe Pauling made it that way when he determined electronegativities in the '30s.
Δ
EN
C
−
Cl
=
1.0
Δ
EN
C
−
H
=
0.4
Δ
EN
C
−
C
=
0.0
Δ
EN
C
−
O
=
1.0
Δ
EN
O
−
H
=
1.4
So naturally, with the greatest electronegativity difference of
4.0
−
2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
That means generally, the greater the electronegativity difference between two atoms is, the shorter you can expect the bond to be, insofar as the electronegative atom is the same size as another comparable electronegative atom.
However, examining actual data, we would see that on average, in conditions without other bond polarizations occuring:
r
C
−
Cl
≈
177 pm
r
C
−
C
≈
154 pm
r
C
−
O
≈
143 pm
r
C
−
F
≈
135 pm
r
C
−
H
≈
109 pm
r
O
−
H
≈
96 pm
So it is not necessarily the least electronegativity difference that gives the longest bond.
Therefore, you cannot simply consider electronegativity. Examining the radii of the atoms, you should notice that chlorine is the biggest atom in the compound.
r
Cl
≈
79 pm
r
C
≈
70 pm
r
H
≈
53 pm
r
O
≈
60 pm
So assuming the answer is truly
C
−
C
, what would have to hold true is that:
The
C
−
F
bond polarization makes the carbon more electropositive (which is true).
The now more electropositive carbon wishes to attract bonding pairs from chlorine closer, thereby shortening the
C
−
Cl
bond, and potentially the
C
−
H
bond (which is probably true).
The shortening of the
C
−
Cl
bond is somehow enough to be shorter than the
C
−
C
bond (this is debatable).
C. It's so rewarding, people feel emotionally high and fulfilled when they're done.
In volunteering, your primary motivation is to extend your help or assistance and make other people happy. Seeing people happy because of what you are doing, it the ultimate reward of volunteering. Happiness gained from this experience is priceless. It is worth more than any freebies or any material gains you will receive.
