Shape of PCl₆⁻¹, is octahedral.
Hybrdisation of PCl₆⁻¹ is sp³d².
This can be seen the image attached.
The angle between phosphorous and chlorine is 90⁰C. As it has octahedral geometry.
So the answer is as follows:
Shape of PCl₆⁻¹, is octahedral.
Hybrdisation of PCl₆⁻¹ is sp³d².
The angle between phosphorous and chlorine is 90⁰C.
