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Answer:
In the kinetic molecular theory, the molecules of an ideal gas are in constant random motion inside the container of the gas, and the pressure of the gas (which is the pressure exerted by the molecules in their collisions with the walls of the container) arise from this random motion of the molecules.
The main assumptions of the kinetic theory of gases are:
- The gas consists of a large number of molecules that collide between each other and the walls of the container; all these collisions are elastic
- The duration of the collisions is negligible compared to the time between the collisions
- The number of molecules is so large that statistics can be applied
- Intermolecular forces between the molecules are negligible (except during the collisions)
- The volume of the molecules is negligible compared to the volume of the container
In particular, the pressure of the gas is directly proportional to the average kinetic energy of the molecules, according to the equation:
where
p is the pressure of the gas
V is the volume of the container
K is the average kinetic energy of the molecules in the gas
We see that as the pressure is higher, the higher the kinetic energy of the particles: this means that the molecules will move faster, on average.
Therefore in this problem, the gas that exerts a pressure of 1.5 atm will have molecules moving faster than the molecules of the gas exerting a pressure of only 1.0 atm.
Answer:
The ¹³C-NMR Spectrum of <em>tert</em>-butyl alcohol will show only two signals.
(i) Signal at around 31 ppm:
This signal towards upfield is for the carbon atoms which are more shielded and are having rich electron surroundings. The height of peak at y-axis shows the number of carbon atoms as compared to other peaks. In this case it is three times the height of second signal hence, it shows that this peak corresponds to three carbon atoms.
(ii) Signal at around 70 ppm:
This signal towards downfield is for the carbon atom which is more deshielded and is having electron deficient surrounding. As compared to the second signal the height of this peaks corresponds to only one carbon. And the deshielded environment shows that this carbon is directly attached to an electronegative element.
