Longer hydrocarbon molecules have a stronger intermolecular force. More energy is needed to move them apart so they have higher boiling points . This makes them less volatile and therefore less flammable

6 0

3 years ago

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Anybody know chemistry Grahams law ?

sukhopar [10]

There is two different types but i’ll just do both meanings just incase.

Graham's Law of Diffusion: the rate of diffusion of one gas through another is inversely proportional to the square root of the density of the gas.

Graham's Law of Effusion: the rate of effusion of a gas is inversely proportional to the square root of the density of the gas.

hopes this helps..!

7 0

3 years ago

What does an object's apparent size depend on?

ipn [44]

Answer:

D. its actual size and distance from an observer

Explanation:

haha aint i the brainliest

jst kidding

hope it helped u

3 0

3 years ago

It is proposed to use Liquid Petroleum Gas (LPG) to fuel spark-ignition engines. A typical sample of the fuel on a volume basis

Norma-Jean [14]

Answer:

The overall balanced combustion reaction is written as :

$0.7C_3H_8 \ + \ 0.05C_4H_{10} \ + \ 0.25 C_3H_6 \ + \ x(O_2 \ + \ 3.76N_2) ---> 3.05CO_2 \ + \ 3.8H_2O \ + \ 18.612N_2$

$(F/A)_{stoichiometric} = 0.0424$

$(A/F)_{stoichiometric} = 23.562$

the higher heating values $(HHV)_f$ per unit mass of LPG = 49.9876 MJ/kg

the lower heating values $(LHV)_f$ per unit mass of LPG = 46.4933 MJ/kg

Explanation:

The stoichiometric equation can be expressed as :

$0.7C_3H_8 \ + \ 0.05C_4H_{10} \ + \ 0.25 C_3H_6 \ + \ x(O_2 \ + \ 3.76N_2) ---> aCO_2 \ + \ bH_2O \ + \ cN_2$

Now, equating the coefficient of carbon; we have:

(0.7×3)+(0.05×4)+(0.25×3) = a

a = 3.05

Also, Equating the coefficient of hydrogen : we have:

(0.7 × 8) +(0.05 × 10) + ( 0.25 × 6) = 2 b

2b = 7.6

b = 3.8

Equating the coefficient of oxygen

2x = 2a + b

$x = \frac{2a+b}{2} \\ \\ x = \frac{2(3.05)+3.8}{2} \\ \\ x = 4.95$

Equating the coefficient of Nitrogen

$c = 3.76x \\ \\ c = 3.76 *4.95 \\ \\ c = 18.612$

Therefore, The overall balanced combustion reaction can now be written as :

$0.7C_3H_8 \ + \ 0.05C_4H_{10} \ + \ 0.25 C_3H_6 \ + \ x(O_2 \ + \ 3.76N_2) ---> 3.05CO_2 \ + \ 3.8H_2O \ + \ 18.612N_2$

Now; To determine the stoichiometric F/A and A/F ratios; we have:

$(F/A)_{stoichiometric} = \frac{n_f}{n_a } \\ \\ (F/A)_{stoichiometric} = \frac{1}{4.95*(1+3.76)} \\ \\ (F/A)_{stoichiometric} = 0.0424$

$(A/F)_{stoichiometric} = \frac{n_a}{n_f } \\ \\ (A/F)_{stoichiometric} = \frac{4.95*(1+3.76)}{1} \\ \\ (A/F)_{stoichiometric} = 23.562$

What are the higher and lower heating values per unit mass of LPG?

Let calculate the molecular mass of the fuel in order to determine their mass fraction of the fuel components.

Molecular mass of the fuel $M_f = (0.7*M_{C_3H_5} ) + (0.05 *M_{C_4H_{10}}) + (0.25*M _{C_3H_6})$

= 30.8 + 2.9 + 10.5

= 44.2 kg/mol

Mass fraction of the fuel components can now be calculated as :

$m_{C_3H_8} = \frac{30.8}{44.2} \\ \\ m_{C_3H_8} = 0.7 \\ \\ \\ m_{C_4H_{10}} = \frac[2.9}{44.2} \\ \\ m_{C_4H_{10}} = 0.06 \\ \\ \\ m_{C_3H_6} = \frac{10.5}{44.2} \\ \\ m_{C_3H_6} = 0.24$

Finally; calculating the higher heating values $(HHV)_f$ per unit mass of LPG; we have:

$(HHV)_f=(0.7 * HHV_{C_3H_8}) + (0.06 *HHV_{C_4H_{10}})+(0.24*HHV_{C_3H_6} \\ \\ (HHV)_f=(0.7*50.38)+(0.06*49.56)+(0.24*48.95) \\ \\ (HHV)_f=49.9876 \ MJ/kg$

calculating the lower heating values $(LHV)_f$ per unit mass of LPG; we have:

$(LHV)_f = (HHV)_f - \delta H_w \\ \\ (LHV)_f = (HHV)_f - [\frac{m_w}{m_f}h_{vap}] \\ \\ (LHV)_f = 49.9876 \ MJ/kg - [\frac{3.8*18}{44.2}*2.258 \ MJ/kg] \\ \\ (LHV)_f = 46.4933 \ M/kg$

7 0

3 years ago