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Svetach [21]
3 years ago
10

In which region of the carbon-13 NMR spectrum would you expect to find a resonance for the carbonyl group of an aliphatic ketone

? The given chemical shift ranges are approximate.
A. 50-80 ppm
B. 180-210 ppm
C. 100-150 ppm
D. 65-85 ppm
E. 9-10 ppm
F. 110-170 ppm
Chemistry
1 answer:
Mkey [24]3 years ago
6 0

Answer:

Option B 180-210 ppm

Explanation:

C-13 NMR tells about the carbon skeleton and it is similar to proton NMR. Reference compound in C-13 NMR is tetramethylsilane (TMS) in which chemical shift of carbon is considered to be 0.0 ppm.

Chemical shift of carbon having different hybridization is different.

For example, chemical shift of sp3 hybridized carbon is in the region of 0 to 90 ppm.

Chemical shift of sp2 hybridized carbon is in the region of  110 to 220 ppm.

In aliphatic ketone, the carbolyl carbon atom is sp2 hybridized. So, C-13 chemical chemical shift range for carboly carbon is 110-220 ppm

Therefore, among the given option, option B is correct.

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Calculate the mass of aluminum that would have the same number of atoms as 6.35 g of cadmium ​
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Answer:

1.62 g of Al contain the same number of atoms as 6.35 g of cadmium have.

Explanation:

Given data:

mass of cadmium = 6.35 g

Number of atoms of aluminum as 6.35 g cadmium contain = ?

Solution:

Number of moles of cadmium = 6.35 g/ 112.4 g/mol

Number of moles of cadmium = 0.06 mol

Number of atoms of cadmium:

1 mole = 6.022×10²³ atoms of cadmium

0.06 mol × 6.022×10²³ atoms of cadmium/ 1mol

0.36×10²³ atoms of cadmium

Number of atoms of Al:

Number of atoms of Al = 0.36×10²³ atoms

1 mole =  6.022×10²³ atoms

0.36×10²³ atoms × 1 mol   /6.022×10²³ atoms

0.06 moles

Mass of aluminum:

Number of moles = mass/molar mass

0.06 mol = m/ 27 g/mol

m = 0.06 mol ×27 g/mol

m = 1.62 g

Thus, 1.62 g of Al contain the same number of atoms as 6.35 g of cadmium have.

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