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Readme [11.4K]
2 years ago
15

112 g of aluminum carbide react with 174 g water to produce methane and aluminum hydroxide in the reaction shown below.

Chemistry
1 answer:
dolphi86 [110]2 years ago
8 0

<u>Answer:</u> 4.999 moles of excess reactant will be left over.

<u>Explanation:</u>

Limiting reagent is defined as the reagent which is completely consumed in the reaction and limits the formation of the product.

Excess reagent is defined as the reagent which is left behind after the completion of the reaction.

The number of moles is defined as the ratio of the mass of a substance to its molar mass.

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}       .....(1)

Given mass of aluminium carbide = 112 g

Molar mass of aluminium carbide = 143.96 g/mol

Putting values in equation 1:

\text{Moles of aluminium carbide}=\frac{112g}{143.96g/mol}=0.778mol

For the given chemical reaction:

2Al_4C_3(s)+12H_2O(l)\rightarrow 3CH_4(g)+4Al(OH)_3(s)

By the stoichiometry of the reaction:

2 moles of aluminium carbide reacts with 12 moles of water

So, 0.778 moles of aluminium carbide will react with = \frac{12}{2}\times 0.778=4.668 mol of water

Given mass of water = 174 g

Molar mass of water = 18 g/mol

Putting values in equation 1:

\text{Moles of water}=\frac{174g}{18g/mol}=9.667mol

Moles of excess reactant (water) left = 9.667 - 4.668 = 4.999 moles

Hence, 4.999 moles of excess reactant will be left over.

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A 265-mL flask contains pure helium at a pressure of 751 torrs. A second flask with a volume of 465 mL contains pure argon at a
Nadya [2.5K]

Answer:

Total Pressure = 745.6 torr

Partial Pressure of He = 272.8 torr

Partial Pressure of Ar =  472.8 torr

Explanation:

Step 1: Data given

Volume of the flask helium = 265 mL

Pressure in the helium flask = 751 torr = 751/760 atm

Volume of the flask argon = 465 mL

Pressure in the argon flask = 727 torr = 727/760 atm

The total pressure exerted by a gaseous mixture is equal to the sum of the partial pressures of each individual component in a gas mixture.

Step 2: Calculate total volume

Total volume = 265 mL + 465 mL = 730 mL =  0.730 L

Step 3: Boyle's Law:

P1V1=P2V2

⇒ with P1 = total pressure gas exerts in its own flask

 ⇒ with V1 = volume of flask with stopcock valve closed

 ⇒ with P2 = partial pressure of gas exerts on total volume of both flasks when stopcock valve is opened  

 ⇒ with V2 = total volume of both flasks with stopcock valve opened

Helium using Boyle's Law equation from above:

P1V1=P2V2

⇒ with P1 = Pressure of helium = 751 /760 = 0.98816 atm

 ⇒ with V1 = volume of helium = 0.265 L

 ⇒ with P2 = The new partial pressure of helium

 ⇒ with V2 = total volume = 0.730 L

(0.98816 atm)(0.265L)=P2(0.730L)

P2=0.359 atm

Argon using Boyle's Law equation from above:

P1V1=P2V2

⇒ with P1 = Pressure of argon = 727/760 = 0.95658 atm

 ⇒ with V1 = volume of argon = 0.465 L

 ⇒ with P2 = The new partial pressure of argon

 ⇒ with V2 = total volume = 0.730 L

(0.95658 atm)(0.465L)=P2(0.730L)

P2=0.609 atm

Step 4: Convert pressure in atm to torr

Pressure helium = 0.359 atm = 272.8 torr

Pressure argon = 0.609 atm = 472.8 torr

Step 5: Calculate Total pressure

Ptotal = P(He)+P(Ar)

⇒ Pt  = total pressure of the gas mixture

⇒ P(He) = partial pressure of Helium

 ⇒ P(Ar)  = partial pressure of Argon

Pt = 272.8 torr + 472.8 torr

Pt = 745.6 torr

Total Pressure = 745.6 torr

Partial Pressure of He = 272.8 torr

Partial Pressure of Ar =  472.8 torr

5 0
3 years ago
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