Answer:
Mass = 547.02 × 10⁻²³g
Explanation:
Given data:
Number of atoms of Al = 122 atom
Mass in gram = ?
Solution:
Avogadro number:
The given problem will solve by using Avogadro number.
It is the number of atoms , ions and molecules in one gram atom of element, one gram molecules of compound and one gram ions of a substance. The number 6.022 × 10²³ is called Avogadro number.
1 mole = 6.022 × 10²³ atoms
122 atom/6.022 × 10²³ atoms × 1 mol
20.26× 10⁻²³ mol
Mass in gram:
Mass = number of moles × molar mass
Mass = 20.26× 10⁻²³ mol × 27 g/mol
Mass = 547.02 × 10⁻²³g
Answer:
a)
,
, b)
, 
Explanation:
a) The ideal gas is experimenting an isocoric process and the following relationship is used:

Final temperature is cleared from this expression:


The number of moles of the ideal gas is:



The final temperature is:


The final pressure is:



b) The ideal gas is experimenting an isobaric process and the following relationship is used:

Final temperature is cleared from this expression:




The final volume is:



Answer:
pH = 12.15
Explanation:
To determine the pH of the HCl and KOH mixture, we need to know that the reaction is a neutralization type.
HCl + KOH → H₂O + KCl
We need to determine the moles of each compound
M = mmol / V (mL) → 30 mL . 0.10 M = 3 mmoles of HCl
M = mmol / V (mL) → 40 mL . 0.10 M = 4 mmoles of KOH
The base is in excess, so the HCl will completely react and we would produce the same mmoles of KCl
HCl + KOH → H₂O + KCl
3 m 4 m -
1 m 3 m
As the KCl is a neutral salt, it does not have any effect on the pH, so the pH will be affected, by the strong base.
1 mmol of KOH has 1 mmol of OH⁻, so the [OH⁻] will be 1 mmol / Tot volume
[OH⁻] 1 mmol / 70 mL = 0.014285 M
- log [OH⁻] = 1.85 → pH = 14 - pOH → 14 - 1.85 = 12.15
Answer:
11.31g NaClO₂
Explanation:
<em> Is given 250mL of a 1.60M chlorous acid HClO2 solution. Ka is 1.110x10⁻². What mass of NaClO₂ should the student dissolve in the HClO2 solution to turn it into a buffer with pH =1.45? </em>
It is possible to answer this question using Henderson-Hasselbalch equation:
pH = pKa + log₁₀ [A⁻] / [HA]
<em>Where pKa is -log Ka = 1.9547; [A⁻] is the concentration of the conjugate base (NaClO₂), [HA] the concentration of the weak acid</em>
You can change the concentration of the substance if you write the moles of the substances:
[Moles HClO₂] = 250mL = 0.25L×(1.60mol /L) = <em>0.40 moles HClO₂</em>
Replacing in H-H expression, as the pH you want is 1.45:
1.45 = 1.9547 + log₁₀ [Moles NaClO₂] / [0.40 moles HClO₂]
-0.5047 = log₁₀ [Moles NaClO₂] / [0.40 moles HClO₂]
<em>0.3128 = </em>[Moles NaClO₂] / [0.40 moles HClO₂]
0.1251 = Moles NaClO₂
As molar mass of NaClO₂ is 90.44g/mol, mass of 0.1251 moles of NaClO₂ is:
0.1251 moles NaClO₂ ₓ (90.44g / mol) =
<h3>11.31g NaClO₂</h3>