Hi, here is a basic summary of what we did in a lab; there were 3 reactions: The procedure: Reaction 1: Solid sodium hydroxide dissolves in water to form an aqueous solution of ions. NaOH(s)-> Na+(aq) + OH-(aq) ΔH1=-34.121kJ Reaction 2: Solid sodium hydroxide reacts with an aqueous solution of HCl to form water and an aqueous solution of sodium chloride. NaOH(s) + H+(aq) + Cl-(aq) -> H2O + Na+(aq) + Cl-(aq) ΔH2=-83.602kJ Reaction 3: An aqueous solution of sodium hydroxide reacts with an aqueous solution of HCl to form water an an aqueous solution of sodium chloride. H+(aq) + OH-(aq) + Na+(aq) + Cl-(aq) -> H2O + Na+(aq) + Cl-(aq) ΔH3= -50.2kJ The ΔH values were calculated by dividing the heat gained by the number of moles (each reaction had 0.05moles of NaOH) The problem: Net ionic equations for reaction 2 & 3: 2: NaOH(s) + H+(aq) -> H2O + Na+(aq) 3: H+(aq) + OH-(aq) -> H2O i) In reaction 1, ΔH1 represents the heat evolved as solid NaOH dissolves. Look at the net ionic equations for reactions 2 and 3 and make similar statements as to what ΔH2 and ΔH3 represent. ii) Compare ΔH2 with (ΔH1 + ΔH3). Explain in sentences the similarity between these two values by using your answer to #5 above. Attempt at answering: i) Firstly, ΔH2 represents the heat evolved as the hydrogen ion displaces the sodium ion, creating a single displacement reaction. ΔH3 represents the heat evolved as the hydrogen and hydroxide ion form water via a neutralization reaction. ii) ΔH2 is equal to (or supposed to be, this is a source of error while calculating) (ΔH1 + ΔH3). The similarity between these two values is that .. (this is where I get confused!)
Source https://www.physicsforums.com/threads/calorimetry-help-chemistry.399653/
Answer:
B, D, C
Explanation:
the solution may have more than one solute, a solution is a homogenous mixture of 2 or more substances and not all solutions are liquid
Answer:
The number of moles = 0.06 moles
Explanation:
i) Formula
Number of moles = Mass of the sample ÷ Molar masses of the substances
ii) Number of moles = 10.0 ÷ (137)+(19×2)
= 10.0 ÷ 175
= 0.06 moles
Correct Question:
A chemist measures the enthalpy change ΔH during the following reaction: Fe(s) + 2HCl(g)-->FeCl2(s) + H2 ΔH=-157.0 kJ. Use this information to complete the table below. Round each of your answers to the nearest kJ/mol
Answer:
-314 kJ
+628 kJ
+157 kJ
Explanation:
The enthalpy change of a reaction measures the amount of heat that is lost or gained by it. If ΔH >0 the heat is gained, and the reaction is called endothermic, if ΔH<0, the heat is lost, and the reaction is called exothermic.
If the reaction is inverted, the value of ΔH is inverted too (the opposite endothermic reaction is exothermic), and if the reaction is multiplied by a constant, ΔH will be multiplied by it too.
1) 2Fe(s) + 4HCl --> 2FeCl2(s) + 2H2(g)
This reaction is the product of the given reaction by 2, so
ΔH = 2*(-157) = -314 kJ
2) 4FeCl2(s) + 4H2(g) --> 4Fe(s) + 8HCl(g)
This reaction is the inverted reaction given multiplied by 4, so
ΔH = 4*(157) = +628 kJ
3) FeCl2(s) + H2(g) --> Fe(s) + 2HCl
This reaction is the inverted reaction given, so
ΔH = +157 kJ