Answer:
Br- Withdraws electrons inductively
Donates electrons by resonance
CH2CH3 - Donates electrons by hyperconjugation
NHCH3- Withdraws electrons inductively
Donates electrons by resonance
OCH3 - Withdraws electrons inductively
Donates electrons by resonance
+N(CH3)3 - Withdraws electrons inductively
Explanation:
A chemical moiety may withdraw or donate electrons by resonance or inductive effect.
Halogens are electronegative elements hence they withdraw electrons by inductive effect. However, they also contain lone pairs so the can donate electrons by resonance.
Alkyl groups donate electrons by hyperconjugation involving hydrogen atoms.
-NHCH3 and contain species that have lone pair of electrons which can be donated by resonance. Also, the nitrogen and oxygen atoms are very electron withdrawing making the carbon atom to have a -I inductive effect.
+N(CH3)3 have no lone pair and is strongly electron withdrawing by inductive effects.
Answer:
The freezing point of the solution is - 4.39 °C.
Explanation:
We can solve this problem using the relation:
<em>ΔTf = (Kf)(m),</em>
where, ΔTf is the depression in the freezing point.
Kf is the molal freezing point depression constant of water = -1.86 °C/m,
density of water = 1 g/mL.
<em>So, the mass of 575 mL is 575 g = 0.575 kg.</em>
m is the molality of the solution (m = moles of solute / kg of solvent = (465 g / 342.3 g/mol)/(0.575 kg) = 2.36 m.
<em>∴ ΔTf = (Kf)(m</em>) = (-1.86 °C/m)(2.36 m) = <em>- 4.39 °C.</em>
<em>∵ The freezing point if water is 0.0 °C and it is depressed by - 4.39 °C.</em>
<em>∴ The freezing point of the solution is - 4.39 °C.</em>
Because it is a covalent bond meaning that they share the electrons to achieve full valence.
Answer:
a) galvanic cell
b)electrolytic cell
c) i) K=6.27x10'34
ΔG°=198790 J
ii) K=3.58x10'-34
ΔG°= 191070 J
d) E°=0.278 v
ΔG°= -26827 J
Explanation:
a) There are two kinds of an electrochemical cell, the first is called "galvanic cells", and the second "electrolytic cell".
The fuel cells are capable of produce electric energy through chemical reactions. These reactions are often spontaneous. So, the galvanic cell has a negative value for Gibbs free energy.
b) The electrolytic cell increases the value of Gibbs energy, to positive values, due to the reactions are not spontaneous.
c) i) look image attached
ii) k = look image attached
ΔG° = -nFE° = - 6 X 95500 J/vmole x (-0.33 v)
ΔG° =-191070
d) E°= 0.0592 v/n x lg K
E°= 0.0592V / 1 X log 5.0X10'4
E°= 0.278 v
ΔG° = -nFE° = -1 x 96500 J/ vmole x 0.278v
ΔG° = -26827 J
Explanation:
The boiling point of liquid nitrogen, liquid argon, and liquid oxygen are -196°C, -186°C, and -183°C respectively. So, the correct order is nitrogen, argon, oxygen.
