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vampirchik [111]
3 years ago
12

can anyone help me in explaining the metal excess defect in Non stoichiometric defects? i fail to understand it

Chemistry
1 answer:
mars1129 [50]3 years ago
8 0
<span>Non-stoichiometric defects are </span>compounds which contain the combining elements in a ratio different from that required by their stoichiometric formula. The solids with metal excess <span>defect </span>contain metal in excess to the stoichiometric ratio. Such defect is caused due to either of the following reasons:
1. <span>Metal excess Defect due to Anionic Vacancies:
     In this, </span>negative ions may be missing from their lattice sites leaving holes in which the electrons remain entrapped to maintain the electrical neutrality.
2. Metal excess defect due to the presence of extra cations at interstitial sites:
     In this case, there are extra positive ions occupying interstitial sites and the electrons in another interstitial sites to maintain electrical neutrality. The defect may be visualized as the loss of non-metal atoms which leave their electrons behind. The excess metal ions occupy interstitial positions.
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Cerium (IV) ions are strong oxidizing agents in acid ic solution, oxidizing arsenio us acid to arsen ic acid accor ding to the f
kirill [66]

Answer:

0.2042 M is the original concentration of Ce^{4+} (aq) in the titrating solution.

Explanation:

Mass of As_2O_3 = 0.217 g

Moles of As_2O_3=\frac{0.217 g}{198 g/mol}=0.001096 mol

1 mole of As_2O_3 have 2 mole of As  and 1 mole of H_3AsO_3 have 1 mole of As.

So, from 1 mole of As_2O_3 we will have 2 moles of H_3AsO_3

Then from 0.001096 mol of As_2O_3 :

2\times 0.001096 mol=0.002192 mol of H_3AsO_3

2Ce^{4+}(aq)+H_3AsO_3(aq)+3H_2O(l)\rightarrow 2Ce^{3+}(aq)+H_3AsO_4(aq)+2H^+(aq)

According to reaction, 1 mole of H_3AsO_3 reacts with 2 mole of cerium (IV) ions,then 0.002192 mol of

\frac{2}{1}\times 0.002192 mol=0.004384 mol of cerium (IV) ions.

Volume of the  acidic cerium{IV) sulfate = 21.47 ml =0.02147 L

1 mL = 0.001 L

concentration = \frac{Moles}{Volume(L)}

[Ce^{4+}]=\frac{0.004384 mol}{0.02147 L}=0.2042 M

0.2042 M is the original concentration of Ce^{4+} (aq) in the titrating solution.

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3 years ago
In a galvanic cell, electrons are transferred from one half cell to the other as the redox reaction progresses.
tia_tia [17]

the two process that occur in a cell are

oxidation: this is loss of electron by electrode. the metal electrode loaes electrons and get oxidized and forms ions

the ions get migrated to solution


Reduction: here the ions present in solution gains electron and get deposited on electrodes.

so gain of electrons is by ions


electrode gains electrons is where reduction occurs, and the half cell in which the electrode loses electrons is where oxidation occurs.



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