Answer:
2. 
3. 
Explanation:
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2. In this case, we can evidence the problem by which volume and temperature are involved, so the Charles' law is applied to:

Thus, considering the temperatures in kelvins and solving for the final volume, V2, we obtain:

Therefore, we plug in the given data to obtain:

3. In this case, it is possible to realize that the 3.7 moles of neon gas are at 273 K and 1 atm according to the STP conditions; in such a way, considering the ideal gas law (PV=nRT), we can solve for the volume as shown below:

Therefore, we plug in the data to obtain:

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The methane molecule undergoes oxidation and the carbon is oxidized to carbon dioxide and hydrogen to water.
In this reaction there is cleavage of four C-H bonds and two O=O bonds
there will be formation of two C=O bonds and four O-H bonds.
Overall due to more bond cleavage energy there will be evolution of energy. thus combustion is an exothermic reaction.
I pretty sure the answer is a