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tresset_1 [31]
3 years ago
10

Lithium chloride crystallizes in a face-centered cubic unit cell with chloride ions occupying the lattice points and lithium ion

s occupying octahedral holes. How many chloride ions surround each lithium ion in LiCl?
Chemistry
1 answer:
Evgesh-ka [11]3 years ago
7 0

Answer:

6

Explanation:

The coordination number of a particular crystal structure arrangement is defined as the number of nearest neighbor atoms or ions surrounding an atom or ion.

We must note that in salts of the type MX, the coordination number of each ion must be equal. The structure of LiCl is built by placing each unit cell next to another such that ions residing in the corner, edge or face sites are shared between adjacent unit cells. The LiCl is in FCC arrangement.

Hence in LiCl, each Li+ ion is surrounded by 6 chloride ions.

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In a particular experiment, 2.50-g samples of each reagent are reacted. The theoretical yield of lithium nitride is ________ g.
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Answer:

4.18 g

Explanation:

The formula for the calculation of moles is shown below:

moles = \frac{Mass\ taken}{Molar\ mass}

Given: For Li

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<u>Moles of Li  = 2.50 g / 6.94 g/mol = 0.3602 moles</u>

Given: For N_2

Given mass = 2.50 g

Molar mass of N_2 = 28.02 g/mol

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According to the given reaction:

6Li+N_2\rightarrow 2Li_3N

6 moles of Li react with 1 mole of N_2

1 mole of Li react with 1/6 mole of N_2

0.3602 mole of Li react with \frac {1}{6}\times 0.3602 mole of N_2

Moles of N_2 that will react = 0.06 moles

Available moles of N_2 = 0.08924 moles

N_2 is in large excess. (0.08924 > 0.06)

Limiting reagent is the one which is present in small amount. Thus,

Li is limiting reagent.

The formation of the product is governed by the limiting reagent. So,

6 moles of Li gives 2 mole of Li_3N

1 mole of Li gives 2/6 mole of Li_3N

0.3602 mole of Li react with \frac {2}{6}\times 0.3602 mole of Li_3N

Moles of Li_3N = 0.12

Molar mass of Li_3N = 34.83 g/mol

Mass of Li_3N = Moles × Molar mass = 0.12 × 34.83 g = 4.18 g

<u>Theoretical yield = 4.18 g</u>

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