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Pavlova-9 [17]
3 years ago
8

if 3.26 g of FeNO33 is dissolved in enough water to make exactly what is the molar concentration of nitrate ion g

Chemistry
1 answer:
Tanzania [10]3 years ago
5 0

Answer:

0.404M

Explanation:

...<em>To make exactly 100.0mL of solution...</em>

Molar concentration is defined as the amount of moles of a solute (In this case, nitrate ion, NO₃⁻) in 1 L of solution.

To solve this question we need to convert the mass of Fe(NO₃)₃ to moles. As 1 mole of Fe(NO₃)₃ contains 3 moles of nitrate ion we can find moles of nitrate ion in 100.0mL of solution, and we can solve the amount of moles per liter:

<em>Moles Fe(NO₃)₃ -Molar mass: 241.86g/mol-:</em>

3.26g * (1mol / 241.86g) =

0.01348 moles Fe(NO₃)₃ * (3 moles of NO₃⁻ / 1mole Fe(NO₃)₃) =

<em>0.0404 moles of NO₃⁻</em>

In 100mL = 0.1L, the molar concentration is:

0.0404 moles of NO₃⁻ / 0.100L =

<h3>0.404M</h3>
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A 50.0 mL solution of 0.129 M KOH is titrated with 0.258 M HCl. Calculate the pH of the solution after the addition of each of t
kobusy [5.1K]

Answer:

A- pH = 13.12

B- pH = 12.91

C- pH = 12.71

D- pH = 12.43

E- pH = 11.55

F- pH = 7

G- pH = 2.46

H- pH = 1.88

Explanation:

This is a titration of a strong base with a strong acid. The neutralization reaction is: KOH (aq) + HCl (aq) →  H₂O(l) + KCl(aq)

Our pH at the equivalence point is 7, because we have made a neutral salt.

To determine the volume at that point we state the formula for titration:

mmoles of base = mmoles of acid

Volume of base  . M of base = Volume of acid . M of acid

50mL . 0.129M = 0.258 M . Volume of acid

Volume of acid = (50mL . 0.129M) / 0.258 M →  25 mL (Point <u>F</u>)

When we add 25 mL of HCl, our pH will be 7.

A- At 0 mL of acid, we only have base.

KOH → K⁺ + OH⁻

[OH⁻] = 0.129 M

To make more easy the operations we will use, mmol.

mol . 1000 = mmoles → mmoles / mL = M

- log 0.129 = 0.889

14 - 0.889 = 13.12

B-  In this case we are adding, (7 mL . 0.258M) = 1.81 mmoles of H⁺

Initially we have  0.129 M . 50 mL = 6.45 mmoles of OH⁻

1.81 mmoles of H⁺ will neutralize, the 6.45 mmoles of OH⁻ so:

6.45 mmol - 1.81 = 4.64 mmoles of OH⁻

This mmoles of OH⁻ are not at 50 mL anymore, because our volume has changed. (Now, we have 50 mL of base + 7 mL of acid) = 57 mL of total volume.

[OH⁻] = 4.64 mmoles / 57 mL = 0.0815 M

- log 0.0815 M = 1.09 → pOH

pH = 14 - pOH → 14 - 1.09 = 12.91

C- In this case we add (12.5 mL . 0.258M) = 3.22 mmoles of H⁺

<em>Our initial mmoles of OH⁻ would not change through all the titration. </em>

Then 6.45 mmoles of OH⁻ are neutralized by 3.22 mmoles of H⁺.

6.45 mmoles of OH⁻ - 3.22 mmoles of H⁺ = 3.23 mmoles of OH⁻

Total volume is: 50 mL of base + 12.5 mL = 62.5 mL

[OH⁻] = 3.23 mmol / 62.5 mL = 0.0517 M

- log  0.0517 = 1.29 → pOH

14 - 1.11 = 12.71

D- We add (18 mL . 0.258M) = 4.64 mmoles of H⁺

6.45 mmoles of OH⁻ are neutralized by 4.64 mmoles of H⁺.

6.45 mmoles of OH⁻ - 4.64 mmoles of H⁺ = 1.81 mmoles of OH⁻

Total volume is: 50 mL of base + 18 mL = 68 mL

[OH⁻] = 1.81 mmol / 68 mL = 0.0265 M

- log  0.0265 = 1.57 → pOH

14 - 1.57 = 12.43

E- We add (24 mL . 0.258M) = 6.19 mmoles of H⁺

6.45 mmoles of OH⁻ are neutralized by 6.19 mmoles of H⁺.

6.45 mmoles of OH⁻ - 6.19 mmoles of H⁺ = 0.26 mmoles of OH⁻

Total volume is: 50 mL of base + 24 mL = 74 mL

[OH⁻] = 0.26 mmol / 74 mL = 3.51×10⁻³ M

- log  3.51×10⁻³  = 2.45 → pOH

14 - 2.45 = 11.55

F- This the equivalence point.

mmoles of OH⁻ = mmoles of H⁺

We add (25 mL . 0.258M) = 6.45 mmoles of H⁺

All the OH⁻ are neutralized.

OH⁻  +  H⁺  ⇄   H₂O              Kw

[OH⁻] = √1×10⁻¹⁴   →  1×10⁻⁷  →  pOH = 7

pH → 14 - 7 = 7

G- In this case we have an excess of H⁻

We add (26 mL . 0.258M ) = 6.71 mmoles of H⁺

We neutralized all the OH⁻ but some H⁺ remain after the equilibrium

6.71 mmoles of H⁺ - 6.45 mmoles of OH⁻ = 0.26 mmoles of H⁺

[H⁺] = 0.26 mmol / Total volume

Total volume is: 50 mL + 26 mL → 76 mL

[H⁺] = 0.26 mmol / 76 mL → 3.42×10⁻³ M

- log 3.42×10⁻³ = 2.46 → pH

H- Now we add (29 mL . 0.258M) = 7.48 mmoles of H⁺

We neutralized all the OH⁻ but some H⁺ remain after the equilibrium

7.48 mmoles of H⁺ - 6.45 mmoles of OH⁻ = 1.03 mmoles of protons

Total volume is 50 mL + 29 mL = 79 mL

[H⁺] = 1.03 mmol / 79 mL → 0.0130 M

- log 0.0130 = 1.88 → pH

After equivalence point, pH will be totally acid, because we always have an excess of protons. Before the equivalence point, pH is basic, because we still have OH⁻ and these hydroxides, will be neutralized through the titration, as we add acid.

5 0
3 years ago
a solution has 23.22% mass/concentration of a particular solvent what is the mass of solute dissolved in 2.5 liter of solvent?
aleksandrvk [35]
Let the mass of the solute be x

So, the equation would be
x/2.5+x ×100 = 23.22
x/2.5+x = 23.22/100
100x = 58.05 + 23.22x
100x - 23.22x = 58.05
76.78x = 58.05
x =0.756 ≈ 0.76 litres
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3 years ago
A red rubber dodge ball sits in a 20.0ºC basement, filled with 3.50L of compressed air. Eager to begin practice for the impendin
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V1 / T1 = V2 / T2
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Which noble gas is closest to magnesium
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If you go backwards two elements, you will find Neon (Ne). If you go forwards six, you will find Argon (Ar).       so the closest will be neon
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Which of the following is not a characteristic of life?
Sophie [7]

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C

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