Air pressure changes with altitude because of issues related to gravity. Molecules have more weight the closer they are to the Earth and more of them move to lower elevations as a result; this causes increased pressure because there are more molecules in number and proximity. Conversely, air at higher elevations has less weight, but also forces pressure on those layers below it, resulting in the molecules closer to the Earth supporting more weight, increasing the pressure
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The Total Mechanical Energy
As already mentioned, the mechanical energy of an object can be the result of its motion (i.e., kinetic energy) and/or the result of its stored energy of position (i.e., potential energy). The total amount of mechanical energy is merely the sum of the potential energy and the kinetic energy.
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