It will be number 1.
NO loses oxygen ie its being reduced to N2
NH3 gains oxygen atom ie its being oxidised to H2O
Explanation:
a) The amount of heat released by coffee will be absorbed by aluminium spoon.
Thus, 
To calculate the amount of heat released or absorbed, we use the equation:

Also,
..........(1)
where,
q = heat absorbed or released
= mass of aluminium = 45 g
= mass of coffee = 180 g
= final temperature = ?
= temperature of aluminium = 
= temperature of coffee = 
= specific heat of aluminium = 
= specific heat of coffee= 
Putting all the values in equation 1, we get:
![45 g\times 0.80J/g^oC\times (T_{final}-24^oC)=-[180 g\times 4.186J/g^oC\times (T_{final}-83^oC)]](https://tex.z-dn.net/?f=45%20g%5Ctimes%200.80J%2Fg%5EoC%5Ctimes%20%28T_%7Bfinal%7D-24%5EoC%29%3D-%5B180%20g%5Ctimes%204.186J%2Fg%5EoC%5Ctimes%20%28T_%7Bfinal%7D-83%5EoC%29%5D)

80.30 °C is the final temperature.
b) Energy flows from higher temperature to lower temperature.Whenever two bodies with different energies and temperature come in contact. And the resulting temperature of both bodies will less then the body with high temperature and will be more then the body with lower temperature.
So, is our final temperature of both aluminium and coffee that is 80°C less than initial temperature of coffee and more than the initial temperature of the aluminum.
What's your question? Am I missing something?
Answer:
Insight
Explanation:
Insight is the understanding of a specific cause and effect within a specific context. The term insight can have several related meanings:
- a piece of information
- the act or result of understanding the inner nature of things or of seeing intuitively (called noesis in Greek)
- an introspection
- the power of acute observation and deduction, discernment, and perception, called intellection or noesis
- an understanding of cause and effect based on identification of relationships and behaviors within a model, context, or scenario (see artificial intelligence)
An insight that manifests itself suddenly, such as understanding how to solve a difficult problem, is sometimes called by the German word Aha-Erlebnis. The term was coined by the German psychologist and theoretical linguist Karl Bühler. It is also known as an epiphany, eureka moment or (for cross word solvers) the penny dropping moment (PDM). Sudden sickening realizations identifying a problem rather than solving it, so Uh-oh rather than Aha moments are further seen in negative insight. A further example of negative insight is chagrin which is annoyance at the obviousness of a solution missed up until the point of insight.