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3 years ago

If you are heating something, you can step away for a moment, as long as you come back very quickly.

Chemistry

1 answer:

Harlamova29_29 [7]3 years ago

5 0

Answer: b. False

Explanation:

The more energetic molecules move to a gas, spread out, and form bubbles when heating happens. When exposed to heat, many of the chemicals used in the laboratory are volatile and harmful (fire).

So leaving a material that you heat for even a second can be very hazardous and negligent.

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What is the most likely reason that nonmetals are electrical insulators

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Since valence shells in nonmetal atoms are almost full, the atoms attract electrons and hold them tightly to fill their valence shells.

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3 years ago

Read 2 more answers

We mix 0.08 moles of chloroacetic acid (ClCH2COOH) and 0.04 moles of

Arte-miy333 [17]

Answer:

A. pH using molar concentrations = 2.56

B. pH using activities = 2.46

C. pH of mixture = 2.56

Explanation:

A. pH using molar concentrations

ClCH₂COOH + H₂O ⇌ ClCH₂COO⁻ + H₃O⁺

HA + H₂O ⇌ A⁻ + H₃O⁺

We have a solution of 0.08 mol HA and 0.04 mol A⁻

We can use the Henderson-Hasselbalch equation to calculate the pH.

$\begin{array}{rcl}\text{pH} & = & \text{pK}_{\text{a}} + \log \left(\dfrac{[\text{A}^{-}]}{\text{[HA]}}\right )\\\\& = & 2.865 +\log \left(\dfrac{0.04}{0.08}\right )\\\\& = & 2.865 + \log0.50 \\& = &2.865 - 0.30 \\& = & \mathbf{2.56}\\\end{array}$

B. pH using activities

(i) Calculate [H⁺]

pH = -log[H⁺]

$\text{[H$^{+}$]} = 10^{-\text{pH}} \text{ mol/L} = 10^{-2.56}\text{ mol/L} = 2.73 \times 10^{-3}\text{ mol/L}$

(ii) Calculate the ionic strength of the solution

We have a solution of 0.08 mol·L⁻¹ HA, 0.04 mol·L⁻¹ Na⁺, 0.04 mol·L⁻¹ A⁻, and 0.00273 mol·L⁻¹ H⁺.

The formula for ionic strength is

$I = \dfrac{1}{2} \sum_{i} {c_{i}z_{i}^{2}}\\\\I = \dfrac{1}{2}\left [0.04\times (+1)^{2} + 0.04\times(-1)^{2} + 0.00273\times(+1)^{2}\right]\\\\= \dfrac{1}{2} (0.04 + 0.04 + 0.00273) = \dfrac{1}{2} \times 0.08273 = 0.041$

(iii) Calculate the activity coefficients

$\ln \gamma = -0.510z^{2}\sqrt{I} = -0.510(-1)^{2}\sqrt{0.041} = -0.510\times 0.20 = -0.10\\\gamma = 10^{-0.10} = 0.79$

(iv) Calculate the initial activity of A⁻

a = γc = 0.79 × 0.04= 0.032

(v) Calculate the pH

$\begin{array}{rcl}\text{pH} & = & \text{pK}_{\text{a}} + \log \left(\dfrac{a_{\text{A}^{-}}}{a_{\text{[HA]}}}\right )\\\\& = & 2.865 +\log \left(\dfrac{0.032}{0.08}\right )\\\\& = & 2.865 + \log0.40 \\& = & 2.865 -0.40\\& = & \mathbf{2.46}\\\end{array}\\$

C. Calculate the pH of the mixture

The mixture initially contains 0.08 mol HA, 0.04 mol Na⁺, 0.04 mol A⁻, 0.05 mol HNO₃, and 0.06 mol NaOH.

The HNO₃ will react with the NaOH to form 0.05 mol Na⁺ and 0.05 mol NO₃⁻.

The excess NaOH will react with 0.01 mol HA to form 0.01 mol Na⁺ and 0.01 mol A⁻.

The final solution will contain 0.07 mol HA, 0.10 mol Na⁺, 0.05 mol A⁻, and 0.05 mol NO₃⁻.

(i) Calculate the ionic strength

$I = \dfrac{1}{2}\left [0.10\times (+1)^{2} + 0.05 \times(-1)^{2} + 0.05\times(-1)^{2}\right]\\\\= \dfrac{1}{2} (0.10 + 0.05 + 0.05) = \dfrac{1}{2} \times 0.20 = 0.10$

(ii) Calculate the activity coefficients

$\ln \gamma = -0.510z^{2}\sqrt{I} = -0.510(-1)^{2}\sqrt{0.10} = -0.510\times 0.32 = -0.16\\\gamma = 10^{-0.16} = 0.69$

(iii) Calculate the initial activity of A⁻:

a = γc = 0.69 × 0.05= 0.034

(iv) Calculate the pH

$\text{pH} = 2.865 + \log \left(\dfrac{0.034}{0.07}\right ) = 2.865 + \log 0.49 = 2.865 - 0.31 = \mathbf{2.56}$

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3 years ago

A student reacts 20.0 mL of 0.248 M H2SO4 with 15.0 mL of 0.195 M NaOH. Write a balanced chemical equation to show this reaction

Molodets [167]

Answer: The concentration of salt (sodium sulfate), sulfuric acid and NaOH in the solution is 0.0418 M, 0.0999 M and 0 M respectively.

Explanation:

To calculate the number of moles for given molarity, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$ .....(1)

For NaOH:

Initial molarity of NaOH solution = 0.195 M

Volume of solution = 15.0 mL = 0.015 L (Conversion factor: 1 L = 1000 mL)

Putting values in equation 1, we get:

$0.195M=\frac{\text{Moles of NaOH}}{0.015L}\\\\\text{Moles of NaOH}=(0.195mol/L\times 0.015L)=2.925\times 10^{-3}mol$

For sulfuric acid:

Initial molarity of sulfuric acid solution = 0.248 M

Volume of solution = 20.0 mL = 0.020 L

Putting values in equation 1, we get:

$0.248M=\frac{\text{Moles of }H_2SO_4}{0.020L}\\\\\text{Moles of }H_2SO_4=(0.248mol/L\times 0.020L)=4.96\times 10^{-3}mol$

The chemical equation for the reaction of NaOH and sulfuric acid follows:

$2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O$

By Stoichiometry of the reaction:

2 moles of NaOH reacts with 1 mole of sulfuric acid

So, $2.925\times 10^{-3}$ moles of KOH will react with = $\frac{1}{2}\times 2.925\times 10^{-3}=1.462\times 10^{-3}mol$ of sulfuric acid

As, given amount of sulfuric acid is more than the required amount. So, it is considered as an excess reagent.

Thus, NaOH is considered as a limiting reagent because it limits the formation of product.

Excess moles of sulfuric acid = $(4.96-1.462)\times 10^{-3}=3.498\times 10^{-3}mol$

By Stoichiometry of the reaction:

2 moles of KOH produces 1 mole of sodium sulfate

So, $2.925\times 10^{-3}$ moles of KOH will produce = $\frac{1}{2}\times 2.925\times 10^{-3}=1.462\times 10^{-3}mol$ of sodium sulfate

For sodium sulfate:

Moles of sodium sulfate = $1.462\times 10^{-3}moles$

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

$\text{Molarity of sodium sulfate}=\frac{1.462\times 10^{-3}}{0.035}=0.0418M$

For sulfuric acid:

Moles of excess sulfuric acid = $3.498\times 10^{-3}mol$

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

$\text{Molarity of sulfuric acid}=\frac{3.498\times 10^{-3}}{0.035}=0.0999M$

For NaOH:

Moles of NaOH remained = 0 moles

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

$\text{Molarity of NaOH}=\frac{0}{0.050}=0M$

Hence, the concentration of salt (sodium sulfate), sulfuric acid and NaOH in the solution is 0.0418 M, 0.0999 M and 0 M respectively.

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3 years ago

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