It's NF3 (one Nitrogen and 3 Flouride)
It should be for the total solution of 93 plus 20 grams which is 113 grams so 93 divided by 113 grams comes to 82.3% sodium sulfate and this can be checked by multiplying 113 grams by 0.823 which results in 93 grams of sodium sulphate.
We have that every gas satisfies the fundamental gas equation, PV=nRT where P is the Pressure, V is the volume of the gas, n are the moles of the gas, R is a universal constant and T is the Temperature in Kelvin. We have that PV/T=nR and during our process, the moles of the gas do not change (no argon enters or escapes our sample). See attached.
The rate constant : k = 9.2 x 10⁻³ s⁻¹
The half life : t1/2 = 75.3 s
<h3>Further explanation</h3>
Given
Reaction 45% complete in 65 s
Required
The rate constant and the half life
Solution
For first order ln[A]=−kt+ln[A]o
45% complete, 55% remains
A = 0.55
Ao = 1
Input the value :
ln A = -kt + ln Ao
ln 0.55 = -k.65 + ln 1
-0.598=-k.65
k = 9.2 x 10⁻³ s⁻¹
The half life :
t1/2 = (ln 2) / k
t1/2 = 0.693 : 9.2 x 10⁻³
t1/2 = 75.3 s
Explanation:
The reaction equation will be as follows.

Calculate the amount of
dissolved as follows.

It is given that
= 0.032 M/atm and
=
atm.
Hence,
will be calculated as follows.
=
= 
= 
or, = 
It is given that 
As, ![K_{a} = \frac{[H^{+}]^{2}}{[CO_{2}]}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5BH%5E%7B%2B%7D%5D%5E%7B2%7D%7D%7B%5BCO_%7B2%7D%5D%7D)
= 
= 
Since, we know that pH = ![-log [H^{+}]](https://tex.z-dn.net/?f=-log%20%5BH%5E%7B%2B%7D%5D)
So, pH = 
= 5.7
Therefore, we can conclude that pH of water in equilibrium with the atmosphere is 5.7.