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nikitadnepr [17]
3 years ago
11

During the workup portion of the reaction of alkenes with HBr as described in the experiment provided, a student transferred the

reaction mixture to a separatory funnel, rinsed the reaction flask with diethyl ether, and added the ether rinses to the separatory funnel. The student then added sodium bicarbonate to the separatory funnel. Extremely vigorous bubbling occurred. What did the student do wrong
Chemistry
1 answer:
inn [45]3 years ago
6 0

Answer:

Explanation:

Because of the acid-base reaction, as sodium bicarbonate is introduced to the separatory funnel, the additional or unreacted HBr reacts vigorously to yield CO2 gas, which exits the separatory funnel together with any dissolved compound(s) in the ether layer. This is due to a wrong and incorrect selection of the solvent mixture and the addition of sodium bicarbonate to an acidic solution.

Nothing to do with it until it has leaked out of the separatory funnel. Even then, the student may separate the components from the remaining reaction mixture by washing the ether coating layer several times with brine water, then running it into a dry sodium sulfate bed and evaporating solvent ether under decreased pressure.

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What is true of tectonic plates?
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3 years ago
86.14 mL of an acid solution was needed to neutralize 30.24 mL of a base solution of unknown concentrations. A second trial is r
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The correct answer is option B.

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Aclosed system contains an equimolar mixture of n-pentane and isopentane. Suppose the system is initially all liquid at 120°C an
garri49 [273]

Explanation:

The given data is as follows.

      T = 120^{o}C = (120 + 273.15)K = 393.15 K,  

As it is given that it is an equimolar mixture of n-pentane and isopentane.

So,            x_{1} = 0.5   and   x_{2} = 0.5

According to the Antoine data, vapor pressure of two components at 393.15 K is as follows.

               p^{sat}_{1} (393.15 K) = 9.2 bar

               p^{sat}_{1} (393.15 K) = 10.5 bar

Hence, we will calculate the partial pressure of each component as follows.

                 p_{1} = x_{1} \times p^{sat}_{1}

                            = 0.5 \times 9.2 bar

                             = 4.6 bar

and,           p_{2} = x_{2} \times p^{sat}_{2}

                         = 0.5 \times 10.5 bar

                         = 5.25 bar

Therefore, the bubble pressure will be as follows.

                           P = p_{1} + p_{2}            

                              = 4.6 bar + 5.25 bar

                              = 9.85 bar

Now, we will calculate the vapor composition as follows.

                      y_{1} = \frac{p_{1}}{p}

                                = \frac{4.6}{9.85}

                                = 0.467

and,                y_{2} = \frac{p_{2}}{p}

                                = \frac{5.25}{9.85}

                                = 0.527  

Calculate the dew point as follows.

                     y_{1} = 0.5,      y_{2} = 0.5  

          \frac{1}{P} = \sum \frac{y_{1}}{p^{sat}_{1}}

           \frac{1}{P} = \frac{0.5}{9.2} + \frac{0.5}{10.2}

             \frac{1}{P} = 0.101966 bar^{-1}              

                             P = 9.807

Composition of the liquid phase is x_{i} and its formula is as follows.

                   x_{i} = \frac{y_{i} \times P}{p^{sat}_{1}}

                               = \frac{0.5 \times 9.807}{9.2}

                               = 0.5329

                    x_{z} = \frac{y_{i} \times P}{p^{sat}_{1}}

                               = \frac{0.5 \times 9.807}{10.5}

                               = 0.467

4 0
3 years ago
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