Answer:
K(48.5°C) = 1.017 E-8 s-1
Explanation:
- CH3Cl + H2O → CH3OH + HCl
at T1 = 25°C (298 K) ⇒ K1 = 3.32 E-10 s-1
at T2 = 48.5°C (321.5 K) ⇒ K2 = ?
Arrhenius eq:
- K(T) = A e∧(-Ea/RT)
- Ln K = Ln(A) - [(Ea/R)(1/T)]
∴ A: frecuency factor
∴ R = 8.314 E-3 KJ/K.mol
⇒ Ln K1 = Ln(A) - [Ea/R)*(1/T1)]..........(1)
⇒ Ln K2 = Ln(A) - [(Ea/R)*(1/T2)].............(2)
(1)/(2):
⇒ Ln (K1/K2) = (Ea/R)* (1/T2-1/T1)
⇒ Ln (K1/K2) = (116 KJ/mol/8.3134 E-3 KJ/K.mol)*(1/321.5 K - 1/298 K)
⇒ Ln (K1/K2) = (13952.37 K)*(- 2.453 E-4 K-1)
⇒ Ln (K1/K2) = - 3.422
⇒ K1/K2 = e∧(-3.422)
⇒ (3.32 E-10 s-1)/K2 = 0.0326
⇒ K2 = (3.32 E-10 s-1)/0.0326
⇒ K2 = 1.017 E-8 s-1
The name for NaCl is Sodium chloride
<h3>Salt and it's examples.</h3>
Salt is defined as the chemical compound that contains both a positively charged cation.and negatively charged anion.
It is formed by the reaction of acid and base is a neutralisation reaction.
Examples of salt include:
- Sodium Chloride or Common Salt (NaCl)
- Sodium Carbonate or Washing Soda (Na2CO3.10H2O)
- Baking Soda or Sodium Bi-carbonate (NaHCO3)
- Bleaching Powder or Calcium Hypochlorite.
Therefore another name for salt is common salt.
Learn more about salt here:
brainly.com/question/13655717
Answer :
(A) The rate expression will be:
![Rate=-\frac{1}{2}\frac{d[HBr]}{dt}=+\frac{d[H_2]}{dt}=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BHBr%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BH_2%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
(B) The average rate of the reaction during this time interval is, 0.00176 M/s
(C) The amount of Br₂ (in moles) formed is, 0.0396 mol
Explanation :
Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.
The given rate of reaction is,

The expression for rate of reaction :
![\text{Rate of disappearance of }HBr=-\frac{1}{2}\frac{d[HBr]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DHBr%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BHBr%5D%7D%7Bdt%7D)
![\text{Rate of disappearance of }H_2=+\frac{d[H_2]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DH_2%3D%2B%5Cfrac%7Bd%5BH_2%5D%7D%7Bdt%7D)
![\text{Rate of formation of }Br_2=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20%7DBr_2%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
<u>Part A:</u>
The rate expression will be:
![Rate=-\frac{1}{2}\frac{d[HBr]}{dt}=+\frac{d[H_2]}{dt}=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BHBr%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BH_2%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
<u>Part B:</u>
![\text{Average rate}=-\frac{1}{2}\frac{d[HBr]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BAverage%20rate%7D%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BHBr%5D%7D%7Bdt%7D)


The average rate of the reaction during this time interval is, 0.00176 M/s
<u>Part C:</u>
As we are given that the volume of the reaction vessel is 1.50 L.
![\frac{d[Br_2]}{dt}=0.00176M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D%3D0.00176M%2Fs)
![\frac{d[Br_2]}{15.0s}=0.00176M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BBr_2%5D%7D%7B15.0s%7D%3D0.00176M%2Fs)
![[Br_2]=0.00176M/s\times 15.0s](https://tex.z-dn.net/?f=%5BBr_2%5D%3D0.00176M%2Fs%5Ctimes%2015.0s)
![[Br_2]=0.0264M](https://tex.z-dn.net/?f=%5BBr_2%5D%3D0.0264M)
Now we have to determine the amount of Br₂ (in moles).



The amount of Br₂ (in moles) formed is, 0.0396 mol
<span>The enthalpy of an intermediate step when used to produce an overall chemical equation should be manipulated in this way:
</span><span>Multiply the enthalpy by –1 if the chemical equation is reversed.
If the forward reaction requires energy, the reverse will produce energy.</span>
I believe the answer is a compound because compounds can be separated when put together while mixtures can not.