<span>Actually, the heat of reaction hrxn s calculated by taking
the sum of the heats of formation of the products minus the sum of the heats of
formation of the reactants. However, at heat of formations of pure elements at
atmospheric conditions is zero, therefore the hf of N2 is not important since
it is zero anyway.</span>
Answer:
i think c should be ur answer
It is important to have the correct bond angles of the different atoms and the shape of the molecule due to following reasons;
Among other properties the polarity of compounds mainly depend upon the shape and bond angles of that particular compound. For example, considering the molecule of water, we already know that it is a polar molecule with partially positive hydrogen atoms and partially negative oxygen atoms and acts as universal solvent. The bond angle in water is about 104.5° with a Bent geometry. Unlike carbon dioxide (CO₂) which has Linear structure with bond angle 180° and is non-polar in nature therefore, the bent geometry in water is responsible for the polarity.
Other properties which can also be predicted by predicting the bond angles along with molecular geometries are;
i) Magnetism
ii) Phase of matter
iii) Color
iv) Reactivity
v) Biological activities <em>e.t.c</em>
Consider the isomerization of butane with equilibrium constant is 2.5 .The system is originally at equilibrium with :
[butane]=1.0 M , [isobutane]=2.5 M
If 0.50 mol/L of butane is added to the original equilibrium mixture and the system shifts to a new equilibrium position, what is the equilibrium concentration of each gas?
Answer:
The equilibrium concentration of each gas:
[Butane] = 1.14 M
[isobutane] = 2.86 M
Explanation:
Butane ⇄ Isobutane
At equilibrium
1.0 M 2.5 M
After addition of 0.50 M of butane:
(1.0 + 0.50) M -
After equilibrium reestablishes:
(1.50-x)M (2.5+x)
The equilibrium expression will wriiten as:
![K_c=\frac{[Isobutane]}{[Butane]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BIsobutane%5D%7D%7B%5BButane%5D%7D)

x = 0.36 M
The equilibrium concentration of each gas:
[Butane]= (1.50-x) = 1.50 M - 0.36M = 1.14 M
[isobutane]= (2.5+x) = 2.50 M + 0.36 M = 2.86 M