Answer:
pH = 5.47
Explanation:
The equilibrium that takes place is:
HIO ↔ H⁺ + IO⁻
Ka = ![\frac{[H+][IO-]}{[HIO]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BH%2B%5D%5BIO-%5D%7D%7B%5BHIO%5D%7D)
= 2.3 * 10⁻¹¹
At equilibrium:
<u>Replacing those values in the equation for Ka and solving for x:</u>
Then [H⁺]=3.39 * 10⁻⁶, thus pH = 5.47
Complete Question
A student is extracting caffeine from water with dichloromethane. The K value is 4.6. If the student starts with a total of 40 mg of caffeine in 2 mL of water and extracts once with 6 mL of dichloromethane
The experiment above is repeated, but instead of extracting once with 6 mL the extraction is done three times with 2 mL of dichloromethane each time. How much caffeine will be in each dichloromethane extract?
Answer:
The mass of caffeine extracted is 
Explanation:
From the question above we are told that
The K value is 
The mass of the caffeine is 
The volume of water is 
The volume of caffeine is 
The number of times the extraction was done is n = 3
Generally the mass of caffeine that will be extracted is
![P = m * [\frac{V}{K * v_c + V} ]^3](https://tex.z-dn.net/?f=P%20%3D%20%20m%20%20%2A%20%20%5B%5Cfrac%7BV%7D%7BK%20%2A%20%20v_c%20%2B%20V%7D%20%5D%5E3)
substituting values
![P = 40 * [\frac{2}{4.6 * 2 + 2} ]^3](https://tex.z-dn.net/?f=P%20%3D%20%2040%20%20%20%2A%20%20%5B%5Cfrac%7B2%7D%7B4.6%20%2A%20%202%20%2B%202%7D%20%5D%5E3)
Q: A
according to this formula, we can get the mole fraction of water (n):
P(solu) = n Pv(water)
when we have Pv(solu) = 22.8 and Pv(water) = 23.8 so by substitution:
22.8 = n * 23.8
n= 0.958
- we need to get the moles of glucose:
moles of water = 500 g(mass weight) / 18 (molar weight)= 27.7 mol
n = moles of water / ( moles of water + moles of glucose)
0.958 = 27.7 / ( 27.7+ moles of glucose)
0.958 moles of glucose + 26.5 = 27.7
0.968 moles of glucose = 1.2
moles of glucose = 1.253 mol
∴ the mass of glucose = no.of glucose moles x molar mass
= 1.253 x 180 = 225.5 g
Q: B
here we also need to get n (mole fraction of water )by using this formula:
Pv(solu) = n Pv(water)
when we have Pv(solu)=132 & Pv(water)=150 so, by substition:
132= n * 150
n = 0.88
so, mole fraction of solution = 1 - 0.88 = 0.12
and we can get after that the moles of water = (mass weight / molar mass)
- no.moles of water = 85 g / 18 g/mol = 4.7 moles
- total moles in solution = moles of water / moles fraction of water
= 4.7 / 0.88 = 5.34 moles
∴ moles of the solution = total moles in solu - moles of water
= 5.34 - 4.7 = 0.64 moles solute
∴ the molar mass of the solute = mass weight of solute / no.of moles of solute
= 53.8 / 0.64 = 84 g/mole
Q: C
moles of urea (NH2)2 CO = mass weight / molar mass
= 4.49 g / 60 g /mol
= 0.07 mol
moles of methanol = mass weight / molar mass
= 39.9 g / 32 g/mol = 1.25 mol
moles fraction of methanol = moles of methanol / (moles of methanol + moles of urea )
moles fraction of methanol = 1.25 / ( 1.25+0.07) = 0.95
by substitution in Pv formula we will be able to get the vapour pressure of the solu :
Pv(solu) = n P°v
Pv(solu) = 0.95 * 89 mm Hg
∴Pv(solu) = 84.55 mmHg
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Alcohol is prohibited in many parts of Texas thus anyone under the age of 21 may not be sold alcohol, including adults. Beer and wine may be purchased from licensed establishments Monday through Friday from 7:00 a.m. to midnight. On Saturday, they may sell them from 7:00 a.m. until 1:00 p.m. Additionally, they may sell on Sundays from noon to midnight. Only liquor stores, nevertheless, are allowed to sell distilled alcohol. On Sundays before noon, restaurants are allowed to serve alcoholic beverages with food. On the other hand, it is prohibited to sell any alcoholic beverages with a volume of more than 17% on Sunday (ABV). On Thanksgiving Day, New Year's Day, or Christmas Day, no establishment may offer any alcoholic beverages. Alcohol from a single producer cannot be sold by a restaurant or other retailer. And alcohol cannot be sold by food trucks.
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